2,2'-(2-nitro-p-phenylene)bis(3,1-benzoxazin-4-one) | 105167-82-6

• 分子结构分类: 有机化合物 - 有机杂环化合物
• 英文名称: 2,2'-(2-nitro-p-phenylene)bis(3,1-benzoxazin-4-one)
• 英文别名: 2-[3-Nitro-4-(4-oxo-3,1-benzoxazin-2-yl)phenyl]-3,1-benzoxazin-4-one
• CAS: 105167-82-6
• 化学式: C₂₂H₁₁N₃O₆
• 分子量: 413.346
• InChiKey: XXKGLWFBWIYJEH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.8
• 重原子数：
  31
• 可旋转键数：
  2
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  123
• 氢给体数：
  0
• 氢受体数：
  8

文献信息

• [EN] TRIARYLMETHANE COMPOUNDS<br/>[FR] COMPOSÉS DE TRIARYLMÉTHANE
  申请人：REUTER CHEMISCHE APPBAU KG

  公开号：WO2019154727A1

  公开（公告）日：2019-08-15

  The present invention relates to triarylmethane compounds of the formula (I), which are suitable as monomers for preparing thermoplastic resins having beneficial optical properties and which can be used for producing optical devices. (I) where R1, R2 are e.g. hydrogen; Y is an alkylene group having 2, 3 or 4 carbon atoms, Ar is selected from mono-or polycyclic aryl and mono-or polycyclic hetaryl; X1, X2, X3, X4 are CH, C-Rx or N, provided that in each ring at most two of X1, X2, X3, X4 are N; Rx is e.g. halogen, CN or CH=CH2. The invention also relates to thermoplastic resins comprising a polymerized unit of the compound of formula (I).

  本发明涉及具有以下式（I）的三芳基甲烷化合物，该化合物适用作为制备具有有益光学性能的热塑性树脂的单体，并可用于生产光学器件。其中R1，R2例如是氢；Y是具有2、3或4个碳原子的烷基基团，Ar选自单环或多环芳基和单环或多环杂芳基；X1、X2、X3、X4是CH、C-Rx或N，要求在每个环中最多有两个是N；Rx例如是卤素、CN或CH=CH2。该发明还涉及包含具有上述式（I）化合物的聚合单元的热塑性树脂。
• [EN] POLYCYCLIC COMPOUNDS<br/>[FR] COMPOSÉS POLYCYCLIQUES
  申请人：REUTER CHEMISCHE APPBAU E K

  公开号：WO2020079225A1

  公开（公告）日：2020-04-23

  The present invention relates to compounds of the formula (I), which are suitable as monomers for preparing thermoplastic resins having beneficial optical properties and which can be used for producing optical devices. In Formula (I), A1, A2 are selected from mono- or bicyclic aromatic radicals and mono- or bicyclic heteroaromatic radicals; X represents e.g. a single bond, O, NH, CR6R7; Y is e.g. absent or represents a single bond, O, NH, CR8R9; R1, R2 are hydrogen, a radical Ar' or a radical Ra; R3 is Alk, O-Alk'-, O-Alk'-[O-Alk']o, O-CH2-Ar-C(O)-, O-C(O)-Ar-C(O)-or O-Alk-C(O)-,where in the last five moieties the left O is bound to A1 and A2, respectively; m, n are 0, 1 or 2; o is an integer from 1 to 10; R4, R5 are e.g. selected from CN and a radical Ra; R6, R8 are e.g. selected from hydrogen, a radical Ar' and a radical Ra; R7, R9 are e.g. selected from hydrogen, C1-C4-alkyl and a radical Ar'; Ra is selected from the group consisting of C≡C-R11 and Ar-C≡C-R11; R11 is e.g. selected from hydrogen, methyl, mono- or polycyclic aryl having from 6 to 26 carbon atoms and mono- or polycyclic hetaryl having a total of 5 to 26 atoms, which are ring members, where 1, 2, 3 or 4 of the ring atoms of hetaryl are selected from nitrogen, sulphur and oxygen, while the remainder of these atoms are carbon atoms, where mono- or polycyclic aryl are unsubstituted or substituted; and Ar is e.g. phenylene or naphthylene. The invention also relates to thermoplastic resins comprising a polymerized unit of the compound of formula (I) and to optical devices made of such resins.

  本发明涉及公式（I）的化合物，这些化合物适用作为单体制备具有有益光学性能的热塑性树脂，并可用于制造光学器件。在公式（I）中，A1、A2选自单环或双环芳香基团和单环或双环杂芳基团；X代表例如单键，O，NH，CR6R7；Y例如缺失或代表单键，O，NH，CR8R9；R1、R2为氢，基团Ar'或基团Ra；R3为Alk，O-Alk'-，O-Alk'-[O-Alk']o，O-CH2-Ar-C(O)-，O-C(O)-Ar-C(O)-或O-Alk-C(O)-，在最后五个基团中，左侧的O分别与A1和A2结合；m、n为0、1或2；o为1到10的整数；R4、R5例如选自CN和基团Ra；R6、R8例如选自氢，基团Ar'和基团Ra；R7、R9例如选自氢，C1-C4-烷基和基团Ar'；Ra选自C≡C-R11和Ar-C≡C-R11的组，R11例如选自氢，甲基，含有6到26个碳原子的单环或多环芳基和含有总共5到26个原子的单环或多环杂芳基，其中环原子中的1、2、3或4个来自氮、硫和氧，其余原子为碳原子，其中单环或多环芳基是未取代或取代的；Ar例如苯基或萘基。该发明还涉及包含公式（I）化合物聚合单元的热塑性树脂以及由这种树脂制成的光学器件。
• Certain polyester compositions which comprise cyclohexanedimethanol, moderate cyclobutanediol, cyclohexanedimethanol, and high trans cyclohexanedicarboxylic acid
  申请人：Moody Leslie Shane

  公开号：US20070232779A1

  公开（公告）日：2007-10-04

  Described as one aspect of the invention are polyester compositions A polyester composition comprising at least one polyester which comprises: (A) a dicarboxylic acid component comprising: i) 70 to 100 mole % of cyclohexanedicarboxylic acid residues or an ester thereof comprising: (a) 80 to 99 mole % trans-cyclohexanedicarboxylic acid residues or an ester thereof; and (b) 1 to 20 mole % cis-cyclohexanedicarboxylic acid residues or an ester thereof; ii) 0 to 30 mole % of aliphatic dicarboxylic acid residues, other than cyclohexanedicarboxylic acid residues, having up to 16 carbon atoms or esters thereof, other than cyclohexanedicarboxylic acid residues; and iii) 0 to 10 mole % of aromatic dicarboxylic acid residues having up to 20 carbon atoms; and (B) a glycol component comprising: i) 5 to 35 mole % of 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues; and ii) 65 to 95 mole % of 1,4-cyclohexanedimethanol residues, 1,3-cyclohexanedimethanol residues, 1,2-cyclohexanedimethanol residues or esters thereof or mixtures thereof, wherein the total mole % of said dicarboxylic acid component is equal to 100 mole %; the total mole % of said glycol component is equal to 100 mole %; wherein the inherent viscosity of said polyester is from 0.35 to 1.2 dL/g as determined in 60/40 (wt/wt) phenol/tetrachloroethane at a concentration of 0.5 g/100 ml at 25° C.; and wherein said polyester has a Tg of from 66 to 120° C. The polyesters may be manufactured into articles.

  本发明的一方面是聚酯组合物，其中包括至少一种聚酯，该聚酯包括：(A) 二羧酸组分，包括：i) 70至100摩尔％的环己二甲酸残基或其酯，包括：(a) 80至99摩尔％的反式环己二甲酸残基或其酯；和(b) 1至20摩尔％的顺式环己二甲酸残基或其酯；ii) 0至30摩尔％的具有高达16个碳原子的脂肪族二羧酸残基（环己二甲酸残基除外）或其酯；以及iii) 0至10摩尔％的具有高达20个碳原子的芳香族二羧酸残基；和(B) 二元醇组分，包括：i) 5至35摩尔％的2,2,4,4-四甲基-1,3-环丁二醇残基；和ii) 65至95摩尔％的1,4-环己二甲醇残基，1,3-环己二甲醇残基，1,2-环己二甲醇残基或其酯或其混合物，其中所述二羧酸组分的总摩尔％等于100摩尔％；所述二元醇组分的总摩尔％等于100摩尔％；其中所述聚酯的固有粘度在60/40（重量/重量）苯酚/四氯乙烷中以0.5 g / 100 ml浓度在25°C下测定为0.35至1.2 dL / g；且所述聚酯的Tg在66至120°C之间。这些聚酯可以制成物品。
• Certain polyester compositions which comprise cyclobutanediol, cyclohexanedimethanol, and high trans-cyclohexanedicarboxylic acid
  申请人：Moody Leslie Shane

  公开号：US20070232778A1

  公开（公告）日：2007-10-04

  Described as one aspect of the invention are polyester compositions comprising at least one polyester which comprises: (A) a dicarboxylic acid component comprising: i) 70 to 100 mole % of cyclohexanedicarboxylic acid residues or an ester thereof comprising: (a) 70 to 98 mole % trans-cyclohexanedicarboxylic acid residues or an ester thereof; and (b) 2 to 30 mole % cis-cyclohexanedicarboxylic acid residues or an ester thereof; ii) 0 to 30 mole % of aliphatic dicarboxylic acid residues, other than cyclohexanedicarboxylic acid residues, having up to 16 carbon atoms or esters thereof, other than cyclohexanedicarboxylic acid residues,; and iii) 0 to 10 mole % of aromatic dicarboxylic acid residues having up to 20 carbon atoms; and (B) a glycol component comprising: i) 1 to 99 mole % of 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues; and ii) 1 to 99 mole % of 1,4-cyclohexanedimethanol residues, 1,3-cyclohexanedimethanol residues, 1,2-cyclohexanedimethanol residues or esters thereof or mixtures thereof, wherein the total mole % of said dicarboxylic acid component is equal to 100 mole %; the total mole % of said glycol component is equal to 100 mole %; wherein the inherent viscosity of said polyester is from 0.35 to 1.2 dL/g as determined in 60/40 (wt/wt) phenol/tetrachloroethane at a concentration of 0.5 g/100 ml at 25° C.; and wherein said polyester has a Tg of from 60 to 155° C. The polyesters may be manufactured into articles.

  本发明的一方面是聚酯组合物，包括至少一种聚酯，其包括：（A）二羧酸成分，包括：i）70至100摩尔％的环己烷二羧酸残基或其酯，包括：（a）70至98摩尔％的反式环己烷二羧酸残基或其酯；和（b）2至30摩尔％的顺式环己烷二羧酸残基或其酯；ii）0至30摩尔％的脂肪族二羧酸残基，除了具有高达16个碳原子的环己烷二羧酸残基或其酯之外；和iii）0至10摩尔％的具有高达20个碳原子的芳香族二羧酸残基；以及（B）乙二醇成分，包括：i）2,2,4,4-四甲基-1,3-环丁二醇残基的1至99摩尔％；和ii）1,4-环己二甲醇残基、1,3-环己二甲醇残基、1,2-环己二甲醇残基或其酯或其混合物的1至99摩尔％；其中，所述二羧酸成分的总摩尔％等于100摩尔％；所述乙二醇成分的总摩尔％等于100摩尔％；其中，所述聚酯的固有粘度为0.35至1.2 dL/g，在60/40（重量/重量）苯酚/四氯乙烷中，在25°C下浓度为0.5 g/100 ml时确定；所述聚酯具有从60°C到155°C的Tg。这些聚酯可以制成物品。
• ULTRAVIOLET ABSORBING COSMETIC
  申请人：TEIJIN LIMITED

  公开号：EP0383941A1

  公开（公告）日：1990-08-29

  An ultraviolet absorbing cosmetic of the invention contains a cyclic imino ester, has excellent ultraviolet absorbing properties and good water resistance, is difficultly soluble in organic solvents, fats and sebum, and is stable and less stimulates the skin. This cosmetic can be applied to the skin without forming erythema thereon even when the skin is exposed to sunlight for a long period of time and can prevent the skin from aging.

  本发明的一种紫外线吸收化妆品含有一种环状亚氨基酯，具有优异的紫外线吸收特性和良好的耐水性，难溶于有机溶剂、脂肪和皮脂，性质稳定，对皮肤的刺激较小。这种化妆品可以涂抹在皮肤上，即使皮肤长期暴露在阳光下也不会形成红斑，并能防止皮肤老化。