[CdI2(pbbm)]2 | 943433-58-7

• 分子结构分类: 有机化合物 - 有机杂环化合物
• 英文名称: [CdI2(pbbm)]2
• 英文别名: [CdI2(1,1'-(1,5-pentadiyl)bis-1H-benzimidazole)]2
• CAS: 943433-58-7
• 化学式: C₃₈H₄₀Cd₂I₄N₈
• 分子量: 1341.23
• InChiKey: YNVNJDCJRDFHGH-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  cadmium(II) iodide 、 1,1'-(1,5-pentamethylene)bis-1H-benzimidazole 以 水 为溶剂， 以68%的产率得到[CdI2(pbbm)]2
  参考文献：
  名称：

  Impact of counteranion on the self-assembly of Cd(II)-containing MOFs: Syntheses, structures and photoluminescent properties

  摘要：

  Three Cd(II)-containing metal-organic frameworks based on 1,1'-(1,5-pentanediyl)bis-1H-benzimidazole (pbbm), namely, {[Cd(NO3)(pbbm)(2)](2) center dot (NO3)(2) center dot H2O}(n) (1), [CdSO4(Pbbm)(2)](n) (2) and [CdI2(pbbm)](2) (3) are prepared systematically by using hydrothermal technique to examine the effects of counteranion on the topology of the resultant network. In complexes 1 and 2, pbbm acts as a bidentate ligand to link two Cd atoms to result in two different 1D chain structures. Complex 3 has a dimeric structure in which two Cd(II) cations are bridged by two pbbm ligands. The significant differences of these MOFs indicate that the counteranions have great impact on the assembling and structures of the resultant MOFs. The photoluminescent properties of these new materials have been studied in the solid state at room temperature. Further investigation reveals that their photoluminescent characteristics obtained from experiments accord with the computed parameters. (c) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2007.02.038