dicyclopentadienylcadmium | 521095-82-9

• 分子结构分类: 有机化合物 - 有机杂环化合物
• 英文名称: dicyclopentadienylcadmium
• 英文别名: cadmocene
• CAS: 521095-82-9
• 化学式: C₁₀H₁₀Cd
• 分子量: 242.599
• InChiKey: MXBKSDKFMLDSDR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.9
• 重原子数：
  11
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  dicyclopentadienylcadmium 在 pyridine 作用下， 以 吡啶 为溶剂， 生成 bis(cyclopentadienyl)bis(pyridine)cadmium(II)
  参考文献：
  名称：

  Fisher, Bart; Mier, Guido P. M. van; Boersma, Jaap, Journal of Organometallic Chemistry, 1987, vol. 322, p. C37 - C40

  摘要：

  DOI：

文献信息

• Syntheses and structural studies of two adducts of cadmocene, [CdCp2. TMEDA] and [CdCp2. PMDETA] (TMEDA  Me2NCH2CH2NMe2, PMDETA  (Me2NCH2CH2)2NMe)
  作者：Donald Barr、Andrew J. Edwards、Paul R. Raithby、Moira-Ann Rennie、Kerry L. Verhorevoort、Domonic S. Wright

  DOI：10.1016/0022-328x(95)05325-j

  日期：1995.5

  Cp(2)Cd.TMEDA 1 and Cp(2)Cd.PMDETA 2 have been synthesized and characterized by spectroscopic studies and by X-ray diffraction studies at low-temperature (153 K). The adducts are present in the crystals as mononuclear complexes. When the denticity of the Lewis base ligands in these adducts is increased (from two in 1 to three in three in 2) the Cd2+ centre requires less electron density from the Cp ligands and the hapticity changes from eta(2-) in 1 to eta(1-) in 2. Complexes 1 and 2 are the first compounds for which pi-bonding of Cp ligands to Cd2+ has been observed in the solid state.