[FeH(2,6-bis(1-((2,6-diisopropylphenyl)imino)ethyl)pyridine)](1+) | 242797-84-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [FeH(2,6-bis(1-((2,6-diisopropylphenyl)imino)ethyl)pyridine)](1+)
• CAS: 242797-84-8
• 化学式: C₃₃H₄₄FeN₃
• 分子量: 538.579
• InChiKey: DJFIDEYEJVAFNQ-DGOWAXEKSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  四氢呋喃 、 2,6-bis[1-(2,6-diisopropylphenylimino)ethyl]pyridineiron(II) chloride 在 Bis(dimethylaluminium)oxid 作用下， 以 四氢呋喃 为溶剂， 生成 [FeH(2,6-bis(1-((2,6-diisopropylphenyl)imino)ethyl)pyridine)](1+) 、 [Fe(2,6-bis(1-((2,6-diisopropylphenyl)imino)ethyl)pyridine)CH2AlMe2](1+) 、 [FeCl(2,6-bis(1-((2,6-diisopropylphenyl)imino)ethyl)pyridine)(THF)](1+) 、 [FeMe(2,6-bis(1-((2,6-diisopropylphenyl)imino)ethyl)pyridine)(THF)](1+)
  参考文献：
  名称：

  Activation of 2,6-Bis(imino)pyridine Iron(II) Chloride Complexes by Methylaluminoxane:  An Electrospray Ionization Tandem Mass Spectrometry Investigation

  摘要：

  The activation of the [2,6-bis(1-((2,6-diisopropylphenyl)imino)ethyl)pyridine]iron(II) chloride complex (1) with methylaluminoxane (MAO) was investigated in tetrahydrofuran (THF) by means of electrospray ionization tandem mass spectrometry (ESI-MS) complemented by LTV-visible spectroscopy studies. The four-coordinated cationic methyl iron(II) complex 2 ([LFe-Me](+), L = 2,6-bis(1-((2,6-diisopropylphenyl)imino)ethyl)pyridine) was identified in the ESI-MS experiment. In addition, the cationic monochloride iron(II) complex 3 ([LFe-Cl](+)), the product of a-H transfer from 2 to trimethylaluminum (TMA) [LFe-CH2AlMe2](+) (4), and the cationic iron hydride complex 5 ([LFe-H](+)) were identified. Correlation of the ESI-MS experiments with LTV-visible studies revealed that 2 and 3 are present in the THF solution as their solvent adducts.

  DOI：

  10.1021/om050351s