copper(II)(N,N'-ethylenebis(5-methoxysalicylidenaminato)) | 53247-87-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: copper(II)(N,N'-ethylenebis(5-methoxysalicylidenaminato))
• 英文别名: Cu(N,N'-ethylene-bis-5-methoxy salicyldiimine)；[Cu(5,5'-OMe-salen)]
• CAS: 53247-87-3
• 化学式: C₁₈H₁₈CuN₂O₄
• 分子量: 389.898
• InChiKey: LJVXDMXNQIUCOT-BYCVLTJGSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  copper(II)(N,N'-ethylenebis(5-methoxysalicylidenaminato)) 在 pyridine 作用下， 以 吡啶 为溶剂， 生成 copper(II)(N,N'-ethylenebis(5-methoxysalicylidenaminato))(pyridine)
  参考文献：
  名称：

  Bhadbhade, Mohan M.; Srinivas, Inorganic Chemistry, 1993, vol. 32, # 26, p. 6122 - 6130

  摘要：

  DOI：
• 作为产物：
  描述：

  bis-(2-hydroxy-5-methoxy-benzylidene)-ethylene-diamine 、 copper diacetate 以 乙醇 、 水 为溶剂， 生成 copper(II)(N,N'-ethylenebis(5-methoxysalicylidenaminato))
  参考文献：
  名称：

  Tanaka, T., Bulletin of the Chemical Society of Japan, 1960, vol. 33, p. 259 - 261

  摘要：

  DOI：

文献信息

• The functionality of the hybrid systems driven by molecular dimension of the guest copper Schiff-base complexes entrapped in Zeolite-Y
  作者：Susheela Kumari、Archana Choudhary、Saumi Ray

  DOI：10.1002/aoc.4765

  日期：2019.3

  On encapsulation inside the supercage of zeolite‐Y planar Cu (II)–Schiff base complexes show the modified structural, optical and functional properties. The electronic effect of the different substituent groups present in the catalyst plays the decisive role towards their reactivity in the homogeneous phase but after the encapsulation in zeolite Y, reactivity is mainly governed by the molecular dimensions

  在沸石-Y平面Cu（II）-Schiff碱配合物的超笼中进行封装时，显示出修饰的结构，光学和功能特性。催化剂中存在的不同取代基的电子效应对其在均相中的反应性起决定性作用，但在将其包封在Y型沸石中后，反应性主要取决于客体配合物的分子尺寸，而不是分子的电子因素。取代基连接在其上。这些系统借助各种表征工具（例如XRD分析，SEM-EDX，AAS，FTIR，XPS，DSC，TGA，
• Copper(II) Complexes of Tridentate Schiff Bases of 5‐Substituted Salicylaldehydes and Diamines – The Role of the Substituent and the Diamine in the Formation of Mono‐, Di‐ and Trinuclear Species – Crystal Structures and Magnetic Properties
  作者：Luca Rigamonti、Antonio Cinti、Alessandra Forni、Alessandro Pasini、Olivo Piovesana

  DOI：10.1002/ejic.200800372

  日期：2008.8

  describe some copper(II) complexes with tridentate anionic Schiff bases, L–, derived from the monocondensation of some 5-substituted salicylaldehydes (5-G-salH, G = H, NO2 and OMe) with ethylenediamine (en) or 1,3-diaminopropane (tn). Mononuclear [CuL(py)]+, dinuclear [Cu2L2]2+ and trinuclear [Cu3L3(μ3-OH)]2+ compounds have been obtained, and factors affecting the nuclearity of complexes were investigated

  我们描述了一些铜 (II) 配合物与三齿阴离子席夫碱 L-，源自一些 5-取代水杨醛（5-G-salH，G = H，NO2 和 OMe）与乙二胺 (en) 或 1 的单缩合， 3-二氨基丙烷 (tn)。获得了单核[CuL(py)]+、双核[Cu2L2]2+和三核[Cu3L3(μ3-OH)]2+化合物，研究了影响配合物核数的因素，发现取决于反应条件， G的性质和二胺的长度。已经确定了七种代表性化合物的晶体结构。还对双核和三核物种进行了磁性研究，并根据结构数据和当前的超交换模型对结果进行了解释。(© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008)
• Studies on the oxidation of CuII complexes of quadridentate Schiff bases derived from salicylaldehyde or ortho-aminophenol
  作者：Alessandro Pasini、Elisa Bernini、Mauro Scaglia、Giancarlo de Santis

  DOI：10.1016/0277-5387(96)00195-7

  日期：1996.9

  The oxidation of various [CuL] (where L are the dianions of quadridentate Schiff bases derived from salicylaldehyde, and 1,2-diaminoethane, namely 2,2′-[1,2-ethanediylbis(nitrilomethylidene)diphenatol], salen, its 1,3-propane homologue, saltn, or from glyoxal and ortho-aminphenol, namely 2,2′-[(ethanediimine)diphenato], glyaph, as well as some of their analogues) has been studied by cyclic voltammetry

  Salen，其1的氧化[CuL]（其中L是衍生自水杨醛和1,2-二氨基乙烷的2,2'-[1,2-乙二基双（亚硝基甲基亚甲基）二酚）的四齿席夫碱的二价阴离子）已经通过循环伏安法研究了，3-丙烷同系物，盐或乙二醛和邻氨基苯酚的盐，即2,2'-[（（乙二亚胺基）苯乙酮]，gliaph以及它们的一些类似物）。阳极扫描显示一个或两个通常不可逆的氧化峰是由Cu II的存在引起的，因为LH 2和[ZnL]在相同条件下均未被氧化。5-NO 2取代的衍生物的氧化在高扫描速率（1 V s -1）。芳香环上具有取代基的配合物的氧化电位表明，这种取代基的电子影响是通过苯甲酸酯而不是偶氮甲胺基团传递到金属中心的。鹰嘴豆属和salten衍生物被氧化的电位高于相应的salen配合物。对用H 2 O 2 / H 5 IO 6混合物氧化的[CuL]样品进行的电子和ESR光谱研究表明，最初形成的[Cu III L] +迅速分解为Cu
• Syntheses and characterization of copper(II) complexes with Schiff-base ligands derived from ethylenediamine, diphenylethylenediamine and nitro, bromo and methoxy salicylaldehyde
  作者：S Zolezzi、A Decinti、E Spodine

  DOI：10.1016/s0277-5387(98)00376-3

  日期：1999.1

  Copper(II) quelates with Schiff bases derived from ethylenediamine, 1R,2R-(+)- or 1S,2S-(-)-1,2-diphenylethylenediamine and 5-X-salicylaldehyde (X=OCH3, H, Br, NO2) have been synthesized and characterized by elemental analysis and IR and UV-visible spectroscopies. The ORD and CD spectra of the chiral ligands and their related complexes have also been measured. The absorption and CD spectra of the metal complexes in the visible region are consistent with near. square planar coordination geometries. Trends in absorption spectra over the series of complexes can be correlated with electronic effects of the substituents at position 5 of the salicylaldehyde. The sign patterns of the CD spectra in both UV and visible regions suggest the prevalence of S and A conformations for the chelate ring in the complexes of Schiff bases derived, respectively, from R,R- and S,S-diamines. Specific features of the CD spectra of the metal complexes are discussed in terms of the exciton chirality method. (C) 1999 Elsevier Science Ltd. All rights reserved.
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Cu: MVol.B4, 173, page 1830 - 1832
  作者：

  DOI：——

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