mer-[Mo(NCO)3(pyridine)3] | 857745-10-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯
• 英文名称: mer-[Mo(NCO)3(pyridine)3]
• 英文别名: mer-[Mo(NCO)3py3]
• CAS: 857745-10-9
• 化学式: C₁₈H₁₅MoN₆O₃
• 分子量: 459.295
• InChiKey: XQGPHEXMHGWNRF-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  吡啶 、 mer-[Mo(NCO)3(pyridine)3]*2pyridine 以 吡啶 为溶剂， 生成 mer-[Mo(NCO)3(pyridine)3]
  参考文献：
  名称：

  Syntheses and crystal structure of first octahedral d-metal complexes containing three and four isocyanato ligands, mer-[Mo(NCO)3py3] · 2py and trans-(py2H)[Mo(NCO)4py2]

  摘要：

  By refluxing of a mixture of (NH4)(2)[MoCl5(H2O)] and KOCN in pyridine, the neutral mer-[Mo(NCO)(3)py(3)] and anionic trans[Mo(NCO)(4)py(2)](-) species originated simultaneously at reflux temperature. After a separation of the water-unsoluble neutral and water-soluble ionic species, the single crystals of compounds [Mo(NCO)(3)py(3)] center dot 2py (1) and (py(2)H)[Mo(NCO)(4)py(2)] (2) have been prepared and crystal structures of both were determined by X-ray crystallography. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2005.01.013