| 405139-54-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• CAS: 405139-54-0
• 化学式: C₃₈H₃₂P₂PtS₂
• 分子量: 809.832
• InChiKey: FNHQOIHSUXPAFQ-FAIYXUOWSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  10.21
• 重原子数：
  43.0
• 可旋转键数：
  8.0
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  2.0

反应信息

• 作为产物：
  描述：

  (dppe)Pt(Cl)₂ 、 bis(benzenethiolato)lead(II) 以 丙酮 为溶剂， 反应 24.0h， 以15%的产率得到
  参考文献：
  名称：

  Oxidative access to flexible {Pt2(μ-SAr)2} square motifs from platinum thiolato complexes with chelating diphosphine

  摘要：

  Platinum(II) aryl thiolate complexes formulated as (P2)Pt(SAr)(2) are prepared from the chelating bis(diphenylphosphino) dimethyltetrathiafulvalene (P2), with aryl thiolate ligands (SAr), such as benzene-thiolate (BT) and 3,5-dimethylbenzenethiolate (DMBT). The structurally characterized neutral (P2) Pt(SAr)(2) complexes afford, upon oxidation with TCNQF(4), dicationic bimetallic Pt(II) complexes formulated as [(P2)Pt(mu-SAr)(2)Pt(P-2)](2+), characterized by a flexible {Pt-2(mu-SAr)(2)} square motif. The magnetic properties of the TCNQF(4)(-) salts of these bimetallic Pt(II) complexes are determined from susceptibility measurements and a tentative rationale for the formation of such {Pt-2(mu-SAr)(2)} square complexes are provided, based on an original oxidative dimerization process. (C) 2012 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2012.07.001