[Mn(bpm)(N3)2]n: A One-Dimensional Coordination Polymer Exhibiting Strong Ferromagnetic−Antiferromagnetic Alternating Interactions
摘要:
Ferromagnetic and antiferromagnetic alternating interactions within and between chains, respectively, were interpreted for a one-dimensional coordination polymer having high-spin (S = 5/2) Mn-II centers bridged by azido ligands, namely, [Mn(bpm)(N-3)(2)](n) (bpm = bis-(pyrazol-1-yl) methane).