bis(O,O'-diethyldithiophosphato)(pyridine)2nickel(II) | 14494-07-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯
• 英文名称: bis(O,O'-diethyldithiophosphato)(pyridine)2nickel(II)
• CAS: 14494-07-6；31168-54-4
• 化学式: C₁₈H₃₀N₂NiO₄P₂S₄
• 分子量: 587.349
• InChiKey: YAFPXUSWPGIJIX-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  bis(O,O'-diethyldithiophosphato)(pyridine)2nickel(II) 以 neat (no solvent) 为溶剂， 生成 镍
  参考文献：
  名称：

  摘要：

  Thermal behaviour of tri(O,O'-diisopropyldithiophosphate)cobalt(III) Co(dptp)(3), and bis (O,O'-diethyldithiophosphate)nickel(II), Ni(detp)(2) and its adducts with pyridine, Ni(detp)(2)(py)(2) or 4-methylpyridine, Ni(detp)(mpy)(2) in a dynamic nitrogen atmosphere was investigated by TG-DTG and DSC techniques, which showed a medium endothermic peak for the evolution process of pyridine(or 4-methylpyridine) and a strong exothermic peak for that of O,O'-diethyldithiophosphate. The thermal stability and decomposition patterns for these compounds were compared and interpreted in terms of structural features such as bond character and steric effects. The kinetic parameters and mechanisms of every decomposition stage involved for all these complexes were obtained employing the non-isothermal kinetic analysis method suggested by Malek et al., which showed the kinetics mechanism for pyrolysis of pyridine(or 4-methylpyridine) is an S-B empirical model with lower activation energy, while that of O,O'-dialkyldithiophosphate is a diffusion model. These results are in accord with the fact that two ligands are of different type.

  DOI：

  10.1023/a:1010156827263
• 作为产物：
  描述：

  nickel(II) bis(O,O'-diethyl dithiophosphate) 在 吡啶 作用下， 以 乙醇 为溶剂， 生成 bis(O,O'-diethyldithiophosphato)(pyridine)2nickel(II)
  参考文献：
  名称：

  含硫配体的过渡族配合物的吸收光谱

  摘要：

  镍（II），铑（III），氯化钯（II），铱（III）和其它中心原子相结合，与二乙基二硫代（DTP - ）二乙基二（DTC -）2,2'-二（氨基乙基）硫醚（泽斯），硫代氨基脲（tscaz）和其他含硫的配体。在光谱化学系列DTP位置-

  DOI：

  10.1016/0022-1902(62)80011-6

文献信息

• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Ni: MVol.C2, 8.21, page 1093 - 1102
  作者：

  DOI：——

  日期：——
• Karipides, D.G., Dissertation abstracts, Diss. Pennsylvania Stete Univ. 1961. S. 1/113, 1961, vol. 22, p. 59/60
  作者：Karipides, D.G.

  DOI：——

  日期：——
• Seel, Fritz; Zindler, Guenter, Chemische Berichte, 1980, vol. 113, # 5, p. 1837 - 1846
  作者：Seel, Fritz、Zindler, Guenter

  DOI：——

  日期：——