Ag2(di-m-n-butoxyformamidinate)2 | 377756-00-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: Ag2(di-m-n-butoxyformamidinate)2
• CAS: 377756-00-8
• 化学式: C₄₂H₅₄Ag₂N₄O₄
• 分子量: 894.652
• InChiKey: QFZGLVSGGMGVKP-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  di-m-n-butoxyformamidine 、 Ammonium hydroxide 、 silver nitrate 以 乙醇 、 水 为溶剂， 以35%的产率得到Ag2(di-m-n-butoxyformamidinate)2
  参考文献：
  名称：

  Synthesis and crystallographic characterization of dinuclear silver complexes supported by N,N′-diarylformamidinates

  摘要：

  Synthesis of two new disilver(I) complexes of diarylformamidinate bearing o-ethoxy (1) and m-butoxy substituents (2) is described. Crystallographic characterization revealed that each Ag center is supported primarily by two N centers in approximate co-linear geometry. Secondary coordination of ethereal 0 center to Ag was also observed in molecule 1. Conformational isomerism exists in the crystal of 2, and is attributed to the low energy-barrier free rotation of aryls. Crystal data: compound I crystallizes in orthorhombic space group Pbca, a = 11. 392(1), b = 15.007(1), c = 19.363(2) Angstrom, Z = 4; compound 2 crystallizes in tetragonal space group P4(2)/n, a = 24.152(2), c = 14.371(2) Angstrom, Z = 8. (C) 2001 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(01)00522-9