4-[2-[2-[2-[4-[25,34-Didodecyl-11-[4-[2-[2-[2-(pyridin-4-ylmethoxy)ethoxy]ethoxy]ethoxy]phenyl]-6-tridecacyclo[28.12.0.02,15.03,8.04,41.09,14.013,18.016,29.017,22.023,28.027,32.031,36.037,42]dotetraconta-1(42),2(15),3,5,7,9,11,13,16,18,20,22,24,26,28,30,32,34,36,38,40-henicosaenyl]phenoxy]ethoxy]ethoxy]ethoxymethyl]pyridine | 1180013-55-1

分子结构分类

有机化合物 - 苯类化合物 - 芘

中文名称

——

中文别名

——

英文名称

4-[2-[2-[2-[4-[25,34-Didodecyl-11-[4-[2-[2-[2-(pyridin-4-ylmethoxy)ethoxy]ethoxy]ethoxy]phenyl]-6-tridecacyclo[28.12.0.02,15.03,8.04,41.09,14.013,18.016,29.017,22.023,28.027,32.031,36.037,42]dotetraconta-1(42),2(15),3,5,7,9,11,13,16,18,20,22,24,26,28,30,32,34,36,38,40-henicosaenyl]phenoxy]ethoxy]ethoxy]ethoxymethyl]pyridine

英文别名

4-[2-[2-[2-[4-[25,34-didodecyl-11-[4-[2-[2-[2-(pyridin-4-ylmethoxy)ethoxy]ethoxy]ethoxy]phenyl]-6-tridecacyclo[28.12.0.02,15.03,8.04,41.09,14.013,18.016,29.017,22.023,28.027,32.031,36.037,42]dotetraconta-1(42),2(15),3,5,7,9,11,13,16,18,20,22,24,26,28,30,32,34,36,38,40-henicosaenyl]phenoxy]ethoxy]ethoxy]ethoxymethyl]pyridine

CAS

1180013-55-1

化学式

C₁₀₂H₁₀₈N₂O₈

mdl

——

分子量

1489.99

InChiKey

RKEUBNGUHPHOSD-UHFFFAOYSA-N

BEILSTEIN

——

EINECS

——

计算性质

辛醇/水分配系数(LogP)：

28.1
重原子数：

112
可旋转键数：

48
环数：

17.0
sp3杂化的碳原子比例：

0.37
拓扑面积：

99.6
氢给体数：

0
氢受体数：

10

上下游信息

上游原料

中文名称	英文名称	CAS号	化学式	分子量
——	2-[2-[2-[4-[25,34-Didodecyl-11-[4-[2-[2-(2-hydroxyethoxy)ethoxy]ethoxy]phenyl]-6-tridecacyclo[28.12.0.02,15.03,8.04,41.09,14.013,18.016,29.017,22.023,28.027,32.031,36.037,42]dotetraconta-1(42),2(15),3,5,7,9,11,13,16,18,20,22,24,26,28,30,32,34,36,38,40-henicosaenyl]phenoxy]ethoxy]ethoxy]ethanol	916771-39-6	C₉₀H₉₈O₈	1307.76

反应信息

作为产物：

描述：

2-[2-[2-[4-[25,34-Didodecyl-11-[4-[2-[2-(2-hydroxyethoxy)ethoxy]ethoxy]phenyl]-6-tridecacyclo[28.12.0.02,15.03,8.04,41.09,14.013,18.016,29.017,22.023,28.027,32.031,36.037,42]dotetraconta-1(42),2(15),3,5,7,9,11,13,16,18,20,22,24,26,28,30,32,34,36,38,40-henicosaenyl]phenoxy]ethoxy]ethoxy]ethanol 、 4-(溴甲基)吡啶氢溴酸盐在 sodium hydride 作用下，以四氢呋喃、 mineral oil 为溶剂，反应 12.0h，以70%的产率得到4-[2-[2-[2-[4-[25,34-Didodecyl-11-[4-[2-[2-[2-(pyridin-4-ylmethoxy)ethoxy]ethoxy]ethoxy]phenyl]-6-tridecacyclo[28.12.0.02,15.03,8.04,41.09,14.013,18.016,29.017,22.023,28.027,32.031,36.037,42]dotetraconta-1(42),2(15),3,5,7,9,11,13,16,18,20,22,24,26,28,30,32,34,36,38,40-henicosaenyl]phenoxy]ethoxy]ethoxy]ethoxymethyl]pyridine

参考文献：

名称：

Zhang, Wei; Jin, Wusong; Fukushima, Takanori, Angewandte Chemie, International Edition, 2009, vol. 48, p. 4747 - 4750

摘要：

DOI：

点击查看最新优质反应信息

文献信息

Zhang, Wei; Jin, Wusong; Fukushima, Takanori, Angewandte Chemie, International Edition, 2009, vol. 48, p. 4747 - 4750

作者：Zhang, Wei、Jin, Wusong、Fukushima, Takanori、Ishii, Noriyuki、Aida, Takuzo

DOI：——

日期：——

同类化合物

顺式-1,2-二(1-芘基)环丁烷顺式-1,2-二(1-芘基)环丁烷顺式-(-)-苯并(a)芘-7,8-二醇-9,10-环氧化物雄甾烷还原黑29 还原黄4 还原金橙G 还原绿2 还原绿1 还原紫3B 还原紫 10 还原深蓝BO 还原橙4 还原橙2 还原兰黑BBN 还原亮橙IRK 试剂N1,N1,N3,N3,N6,N6,N8,N8-Octakis(4-methoxyphenyl)-1,3,6,8-pyrenetetramine 蒽酮紫79 蒽缔蒽酮蒽并(1,2,3,4-ghi)苝蒽嵌蒽蒽[9,1,2-cde]苯并[rst]戊芬萘并[2'.8',2.4]晕苯萘并[2',1',8',7':4,10,5]蒽并[1,9,8-abcd]晕苯萘并[1,8-gh:4,5-g'h']二喹啉萘并(8,1,2-bcd)苝萘并(2,3-a)晕苯萘并(2,1,8-qra)萘并萘-7 12-二酮萘并(1,2,3-mno)醋菲烯萘[2,3-a]芘菲并[1,10,9,8-opqra]苝茚并(1,2,3-cd)芘苯胺,2-氯-3-(苯基甲氧基)- 苯并[xyz]庚芬苯并[wx]萘并[2,1,8,7-hijk]庚省苯并[rst]菲并[1,10,9-cde]戊芬苯并[rst]戊酚-5-甲醛苯并[pqr]四苯-5-基甲酸根苯并[pqr]四苯-11-基甲酸根苯并[pqr]二萘并[8,1,2-bcd:2',1',8'-lmn]苝苯并[p]萘并[1,8,7-ghi]屈苯并[l]芘-8-醇苯并[ghi]苝苯并[e]芘苯并[b]芘-6-基甲醇苯并[b]芘-6,12-二酮苯并[b]芘-3,6-二酮苯并[b]芘-1,6-二酮苯并[a]芘-9,10-环氧化物苯并[a]芘-7-醇