| 1496569-15-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并咪唑类
• CAS: 1496569-15-3
• 化学式: C₁₈H₁₇N₅O₃
• 分子量: 351.365
• InChiKey: KEJAMIPBGPGXKX-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  在 silver nitrate 、 溶剂黄146 作用下， 以 1,4-二氧六环 为溶剂， 反应 24.0h， 以25%的产率得到
  参考文献：
  名称：

  Arylnitration of alkenes by nitration/C–H functionalization cascade using AgNO3 and HOAc

  摘要：

  A novel arylnitration of alkenes by nitration and C-H functionalization cascade process has been developed. This methodology provides an efficient way to construct a variety of nitro-containing oxindoles and dihydroquinolin-2(1H)-ones. In addition, the process exhibits significant functional group tolerance. Moreover, the use of inexpensive and readily available starting materials makes this practical and atom-economical approach particularly attractive. (C) 2014 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2014.02.043

文献信息

• Metal-free carbonitration of alkenes using K2S2O8
  作者：Ya-Min Li、Xiao-Hong Wei、Xi-An Li、Shang-Dong Yang

  DOI：10.1039/c3cc47287f

  日期：——

  A novel metal-free oxidative carbonitration of alkenes by a nitration and C–H functionalization cascade process has been developed. This methodology provides an efficient way to construct valuable nitro-containing oxindoles.

  开发了一种新型的无金属氧化碳氮化烯烃方法，这是通过硝化和C-H官能团化级联过程实现的。该方法为合成有价值的含硝基吲哚酮类化合物提供了一种高效途径。