1,3,3-trimethyl-6'-piperidinyl-6-trifluoromethylspiro[indoline-2,3-naphtho[2,1-b][1,4]oxazine] | 172208-34-3

• 分子结构分类: 有机化合物 - 有机杂环化合物
• 英文名称: 1,3,3-trimethyl-6'-piperidinyl-6-trifluoromethylspiro[indoline-2,3-naphtho[2,1-b][1,4]oxazine]
• 英文别名: 1',3',3'-Trimethyl-6-piperidin-1-yl-6'-(trifluoromethyl)spiro[benzo[f][1,4]benzoxazine-3,2'-indole]
• CAS: 172208-34-3
• 化学式: C₂₈H₂₈F₃N₃O
• 分子量: 479.545
• InChiKey: ICAOQPRXCZFWTM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.9
• 重原子数：
  35
• 可旋转键数：
  1
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.39
• 拓扑面积：
  28.1
• 氢给体数：
  0
• 氢受体数：
  7

反应信息

• 作为产物：
  描述：

  哌啶 、 1,3,3-trimethyl-2-methylene-6-trifluoromethylindoline 、 1-亚硝基-2-萘酚 以 甲醇 为溶剂， 反应 6.25h， 生成 1,3,3-trimethyl-6'-piperidinyl-6-trifluoromethylspiro[indoline-2,3-naphtho[2,1-b][1,4]oxazine]
  参考文献：
  名称：

  一种利用微通道反应器合成螺噁嗪类光致变色染料的方法

  摘要：

  本发明涉及一种利用微通道反应器合成螺噁嗪光致变色染料的方法。在染料合成后期的偶联成环过程中，通过预反应系统分别将含有反应原料的流动相体系温度调整至反应温度后，利用恒流泵将上述流动相分别泵入微通道反应器内进行混合控温反应，得到含有光变染料的溶液，通过浓缩、重结晶、脱色和干燥，获得光致变色染料。本方法利用微通道较高的混合和热交换效率，保证了反应物的充分混合和控温的精确，节能效果好，降低了生产成本，产物纯度高，降低后续处理难度，流动相可重复利用，方便规模化生产，具有广大的应用前景。

  公开号：

  CN113943493A

文献信息

• A non-glaring laminated body, a coated non-glaring laminated body, a non-glaring material, and a method for producing the non-glaring material
  申请人：MGC Filsheet Co., Ltd.

  公开号：EP1916097A2

  公开（公告）日：2008-04-30

  [Problem to be solved] The present invention provides a non-glaring material having an excellent property to cut ultraviolet rays, and having an excellent appearance and optical property as well as easy producibility and processibility, and a method for producing the non-glaring material. [Means to solve the problem] A non-glaring laminated body consisting of two transparent plastic material layers, a polarizing film layer which is held between the two transparent plastic material layers, and a synthetic adhesive layer which adheres the plastic material layer to the polarizing film layer, wherein at least one of the adhesive layers includes a fluorescent whitening agent and an ultraviolet ray absorber.

  [有待解决的问题］ 本发明提供了一种具有优异的紫外线切割性能、优异的外观和光学性能以及易于生产和加工的不刺眼材料，以及生产这种不刺眼材料的方法。 [解决问题的方法］ 一种不刺眼层压体，由两层透明塑料材料层、夹在两层透明塑料材料层之间的偏光膜层和将塑料材料层粘在偏光膜层上的合成粘合剂层组成，其中至少一层粘合剂层包括荧光增白剂和紫外线吸收剂。
• METHOD OF PRODUCING PHOTOCHROMIC RESIN BODY AND METHOD OF PRODUCING FUNCTION-ADDING BASE BODY
  申请人：Nidek Co., Ltd.

  公开号：EP3715435A1

  公开（公告）日：2020-09-30

  A method of producing a photochromic resin body includes a first step, a second step and a third step. In the first step, a sublimable photochromic dye having sublimability is applied to a base body so as to obtain a function-adding base body. In the second step, the function-adding base body obtained in the first step is set to face a resin body, the function-adding base body is heated to sublimate the sublimable photochromic dye applied to the function-adding base body, and the sublimable photochromic dye is deposited on the resin body. In the third step, the resin body on which the sublimable photochromic dye is deposited in the second step is heated to fix the sublimable photochromic dye on the resin body.

  一种生产光致变色树脂体的方法包括第一步、第二步和第三步。在第一步中，将具有升华性的可升华光致变色染料涂抹到基体上，从而获得添加功能的基体。在第二步中，将在第一步中获得的功能增强基体设置为面向树脂体，加热功能增强基体以升华涂在功能增强基体上的可升华光致变色染料，并将可升华光致变色染料沉积在树脂体上。在第三步中，加热在第二步中沉积了可升华光致变色染料的树脂体，以将可升华光致变色染料固定在树脂体上。
• Organic light-emitting display apparatus
  申请人：Samsung Display Co., Ltd.

  公开号：US10249693B2

  公开（公告）日：2019-04-02

  An organic light-emitting display apparatus for selectively realizing circular polarization according to external light conditions, including a substrate; an organic light-emitting device on the substrate; a sealing member on the organic light-emitting device; a phase retardation layer on a surface of the substrate, the organic light-emitting device, or the sealing member; and a linear polarization layer on another surface of the substrate, the organic light-emitting device, or the sealing member, wherein the linear polarization layer is located to be closer to a source of external light than the phase retardation layer, and wherein the linear polarization layer comprises a photochromic material.

  一种根据外部光照条件选择性实现圆偏振的有机发光显示装置，包括基板；基板上的有机发光器件；有机发光器件上的密封部件；基板、有机发光器件或密封部件的一个表面上的相位延迟层，以及基板、有机发光器件或密封部件的另一个表面上的线性偏振层；以及位于基板、有机发光器件或密封部件的另一表面上的线性偏振层，其中线性偏振层的位置比相位延迟层更靠近外部光源，并且线性偏振层包括光致变色材料。
• METHOD OF PRODUCING PHOTOCHROMIC RESIN BODY
  申请人：Nidek Co., Ltd.

  公开号：EP3715435B1

  公开（公告）日：2022-05-11
• NON-GLARING LAMINATED BODY, A COATED NON-GLARING LAMINATED BODY, A NON-GLARING MATERIAL, AND A METHOD FOR PRODUCING THE NON-GLARING MATERIAL
  申请人：KIMURA Hideaki

  公开号：US20080094704A1

  公开（公告）日：2008-04-24

  The present invention provides a non-glaring material having an excellent property to cut ultraviolet rays, and having an excellent appearance and optical property as well as easy producibility and processibility, and a method for producing the non-glaring material. A non-glaring laminated body consisting of two transparent plastic material layers, a polarizing film layer which is held between the two transparent plastic material layers, and a synthetic adhesive layer which adheres the plastic material layer to the polarizing film layer, wherein at least one of the adhesive layers includes a fluorescent whitening agent and an ultraviolet ray absorber.