[Me2SnCl(2-mercaptopyrimidine-1H)] | 248590-61-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二嗪类
• 英文名称: [Me2SnCl(2-mercaptopyrimidine-1H)]
• 英文别名: [Me2SnCl(Spym)]；chloro-dimethyl-pyrimidin-2-ylsulfanylstannane
• CAS: 248590-61-6
• 化学式: C₆H₉ClN₂SSn
• 分子量: 295.38
• InChiKey: OSRGEUGRJBVJRF-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  二甲基二氯化锡 、 2-巯基嘧啶 在 EtONa 作用下， 以 苯 为溶剂， 以79%的产率得到[Me2SnCl(2-mercaptopyrimidine-1H)]
  参考文献：
  名称：

  Syntheses, characterization and crystal structures of diorganotin compounds with 2-mercaptopyrimidine and 4-amino-2-mercaptopyrimidine

  摘要：

  Six diorganotin compounds with 4-amino-2-mercaptopyrimidine (HSapym) and 2-mercaptopyrimidine (HSpym) of the type, [R2SnClmLn]center dot Y (when n = m = 1: L = Spym, R = CH3, Y = 0, 1; R = Bu, Y = 0, 2; L = Sapym, R = Ph, Y = EtOH, 3; when n = 2, m = 0: L = Spym, R = PhCH2, Y = 0, 4; L = Sapym, R = Bu, Y = 2MeOH, 5; R = PhCH2, Y = 3MeOH, 6) have been synthesized. X-ray analysis revealed that the tin environmental in 1-3 is trigonal bipyramidal while that in 4-6 is distorted octahedral. Two coordination modes are found in the organotin(IV) derivatives for HSapym. Additionally the intermolecular Sn center dot center dot center dot S non-bonded interaction was recognized to benefit the construction of an infinite 1D chain structure of compound 1. For the dimer in compound 3, intermolecular N center dot center dot center dot H hydrogen bonding was found. (c) 2005 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2004.11.029