(tris(3,5-dimethylpyrazolyl)methane)Ni(η2-NO3)(η1-NO3) | 898807-75-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 咪唑并吡啶类
• 英文名称: (tris(3,5-dimethylpyrazolyl)methane)Ni(η2-NO3)(η1-NO3)
• 英文别名: (tpm*)Ni(η2-NO3)(η1-NO3)
• CAS: 898807-75-5
• 化学式: C₁₆H₂₂N₈NiO₆
• 分子量: 481.091
• InChiKey: KCHPNOJIIKZVIR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  (tris(3,5-dimethylpyrazolyl)methane)Ni(η2-NO3)(η1-NO3) 、 1-[(3,5-二甲基吡唑-1-基)甲基]-3,5-二甲基吡唑 以 甲醇 、 乙醇 为溶剂， 以48%的产率得到(bis(3,5-dimethylpyrazolyl)methane)(tris(3,5-dimethylpyrazolyl)methane)Ni(η1-NO3)NO3
  参考文献：
  名称：

  Synthesis and structural characterization of bis- and tris(3,5-dimethylpyrazolyl)methane complexes of Ni(NO3)2

  摘要：

  The complexes (tpm*)Ni(eta(2)-NO3)(eta(1)-NO3) (1), [(bpm*)(2)Ni(eta(2)-NO3)]NO3 (2), and [(tpm*)(bpm*)Ni(eta(1)-NO3)]NO3 (3) (tpm* = tris(3,5-dimethylpyrazolyl)methane; bpm* bis(3,5-dimethylpyrazolyl)methane) have been prepared and characterized by IR and UV-Vis spectroscopy and X-ray diffraction studies. These d(8) complexes all adopt variously distorted octahedral structures in the solid state and their magnetic moments are consistent with a paramagnetic state with two impaired electrons. The solution H-1 NMR data show that the paramagnetism is maintained in solution. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2005.09.046
• 作为产物：
  描述：

  nickel(II) nitrate hexahydrate 、 三(3,5-二甲基-1-吡唑基)甲烷 以 丙酮 为溶剂， 以96%的产率得到(tris(3,5-dimethylpyrazolyl)methane)Ni(η2-NO3)(η1-NO3)
  参考文献：
  名称：

  Synthesis and structural characterization of bis- and tris(3,5-dimethylpyrazolyl)methane complexes of Ni(NO3)2

  摘要：

  The complexes (tpm*)Ni(eta(2)-NO3)(eta(1)-NO3) (1), [(bpm*)(2)Ni(eta(2)-NO3)]NO3 (2), and [(tpm*)(bpm*)Ni(eta(1)-NO3)]NO3 (3) (tpm* = tris(3,5-dimethylpyrazolyl)methane; bpm* bis(3,5-dimethylpyrazolyl)methane) have been prepared and characterized by IR and UV-Vis spectroscopy and X-ray diffraction studies. These d(8) complexes all adopt variously distorted octahedral structures in the solid state and their magnetic moments are consistent with a paramagnetic state with two impaired electrons. The solution H-1 NMR data show that the paramagnetism is maintained in solution. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2005.09.046