An epoxidized granular thermoplastic polymer which comprises a shell- like surface layer insoluble in toluene at 25°C is formed on the polymer, and a process for the production of the epoxidized granular thermoplastic polymer characterized in that the process comprises: the first step of epoxidizing a granular thermoplastic polymer in a water medium in the presence of an epoxidizing agent or the epoxidizing agent and a solvent for accelerating an epoxidation reaction and a phosphoric acid series compound; the second step of the washing with water, or the neutralization and washing with water of the epoxidized granular thermoplastic polymer; and the third step, if necessary, of removing the solvent for accelerating epoxidation reaction which may be used in the first step, as well as a process for the production of an epoxidized thermoplastic polymer, characterized in that under the condition in which thermoplastic polymer (A) in the solid-state is dispersed or suspended in water (B), the thermoplastic polymer (A) is epoxidized by a peroxide (C) with the dispersed or suspended state maintained.
一种环氧化粒状热塑性聚合物,在该聚合物上形成一层在25℃下不溶于
甲苯的壳状表面层,以及一种生产该环氧化粒状热塑性聚合物的工艺,其特征在于该工艺包括:第一步 在
水介质中,在环氧化剂或环氧化剂和加速环氧化反应的溶剂以及
磷酸系列 化合物的存在下,环氧化粒状热塑性聚合物; 第二步 用
水洗或中和并用
水洗净环氧化粒状热塑性聚合物;以及一种环氧化热塑性聚合物的生产工艺,其特征在于在固态热塑性聚合物(A)分散或悬浮在
水(B)中的条件下,热塑性聚合物(A)在保持分散或悬浮状态的情况下被过氧化物(C)环氧化。