(2-(diallylamino)phenyl)(phenyl)methanone | 1610460-99-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (2-(diallylamino)phenyl)(phenyl)methanone
• 英文别名: [2-[Bis(prop-2-enyl)amino]phenyl]-phenylmethanone
• CAS: 1610460-99-5
• 化学式: C₁₉H₁₉NO
• 分子量: 277.366
• InChiKey: CUEQGSVLNZUROZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.7
• 重原子数：
  21
• 可旋转键数：
  7
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.11
• 拓扑面积：
  20.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  (2-(diallylamino)phenyl)(phenyl)methanone 在 silica gel 、 lithium diisopropyl amide 作用下， 以 四氢呋喃 、 正己烷 、 乙酸乙酯 为溶剂， 反应 21.0h， 生成 1,7-diallyl-3-benzyl-3-phenylindolin-2-one
  参考文献：
  名称：

  硅胶介导的2-烷基氨基苯基prop-1-yn-3-ols的水胺化/ Semipinacol重排：由炔烃和1-（2-氨基苯基）酮合成2-Oxindoles

  摘要：

  Abstract2‐Alkylaminophenylprop‐1‐yn‐3‐ols, prepared from the lithium diisopropylamide (LDA)‐mediated 1,2‐addition of alkynes to 1‐(2‐aminophenyl) ketones, can be converted to 3,3‐disubstituted 2‐oxindoles by using silica gel in n‐hexane/ethyl acetate (20:1 v/v) as the reaction medium. The utility of the approach as a potential scale‐up strategy for the synthesis of 2‐oxindoles was exemplified by the large‐scale synthesis of one adduct in excellent yield. The synthetic applicability of this chemistry was also demonstrated by the recycling of the silica gel up to 8 times with no apparent loss of activity being observed for the same example.magnified image

  DOI：

  10.1002/adsc.201300911
• 作为产物：
  描述：

  3-溴丙烯 、 2-氨基二苯甲酮 在 potassium carbonate 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 以55%的产率得到(2-(diallylamino)phenyl)(phenyl)methanone
  参考文献：
  名称：

  硅胶介导的2-烷基氨基苯基prop-1-yn-3-ols的水胺化/ Semipinacol重排：由炔烃和1-（2-氨基苯基）酮合成2-Oxindoles

  摘要：

  Abstract2‐Alkylaminophenylprop‐1‐yn‐3‐ols, prepared from the lithium diisopropylamide (LDA)‐mediated 1,2‐addition of alkynes to 1‐(2‐aminophenyl) ketones, can be converted to 3,3‐disubstituted 2‐oxindoles by using silica gel in n‐hexane/ethyl acetate (20:1 v/v) as the reaction medium. The utility of the approach as a potential scale‐up strategy for the synthesis of 2‐oxindoles was exemplified by the large‐scale synthesis of one adduct in excellent yield. The synthetic applicability of this chemistry was also demonstrated by the recycling of the silica gel up to 8 times with no apparent loss of activity being observed for the same example.magnified image

  DOI：

  10.1002/adsc.201300911

文献信息

• BISPHENOL HAVING FLUORENE SKELETON, METHOD FOR PRODUCING SAME, POLYARYLATE RESIN, (METH)ACRYLATE COMPOUND AND EPOXY RESIN WHICH ARE DERIVED FROM THE BISPHENOL
  申请人：TAOKA CHEMICAL CO., LTD.

  公开号：US20190055180A1

  公开（公告）日：2019-02-21

  Provided are a bisphenol represented by the general formula (1), a method for producing the bisphenol, and a polyarylate resin, a (meth)acrylate compound and an epoxy resin which are derived from the bisphenol. In the formula (1), R 1 to R 4 are the same or different, and each represent an alkyl group, an aryl group or a halogen atom, n 1 and n 2 are the same or different, and each represent an integer of 1 to 4, and k 1 to k 4 are the same or different, and each represent 0 or an integer of 1 to 4. When at least one of k 1 to k 4 is 2 or more, corresponding R 1 to R 4 may be the same or different.

  提供的是由通式（1）表示的双酚，一种生产双酚的方法，以及源自双酚的聚苯醚树脂、（甲基）丙烯酸酯化合物和环氧树脂。在式（1）中，R1至R4相同或不同，每个代表一个烷基、芳基或卤素原子，n1和n2相同或不同，每个代表1到4的整数，k1至k4相同或不同，每个代表0或1到4的整数。当k1至k4中至少有一个为2或更大时，相应的R1至R4可以相同或不同。
• Organosilicon compound containing isocyanate group, process for producing same, adhesive, pressure-sensitive adhesive, and coating material
  申请人：SHIN-ETSU CHEMICAL CO., LTD.

  公开号：US10323049B2

  公开（公告）日：2019-06-18

  The purpose of the present invention is to obtain an organosilicon compound containing an isocyanate group by thiol-ene addition reaction from a corresponding organosilicon compound having a mercapto group and an isocyanate compound having a polymerizable group. Provided is a silane coupling agent which includes a specific linking structure in which a sulfur atom is indispensably contained in a linking chain which connects an isocyanate group to a hydrolyzable silyl group. Compared to silane coupling agents for use in existing technologies, this silane coupling agent has enhanced hydrophobicity and an increased organic-moiety proportion due to the sulfur-containing linking structure. Use of this silane coupling agent as an adhesive modifier hence makes it possible to obtain a pressure-sensitive adhesive in which the silane coupling agent has improved compatibility with the resin and is excellent in terms of strength of bonding to and interaction with the matrix resin having hydroxy groups and which is able to have initial reworkability and further have high adhesive force at high temperatures or under high-temperature high-humidity conditions.

  本发明的目的是通过硫醇-烯烃加成反应，从具有巯基的相应有机硅化合物和具有可聚合基团的异氰酸酯化合物中获得含有异氰酸酯基团的有机硅化合物。提供了一种硅烷偶联剂，其中包括一种特定的连接结构，其中硫原子是不可或缺地包含在连接异氰酸酯基团和可水解硅基团的连接链中。与现有技术中使用的硅烷偶联剂相比，由于含硫连接结构，该硅烷偶联剂具有增强的疏水性和有机成分比例增加。因此，使用该硅烷偶联剂作为粘合剂改性剂，可以获得一种压敏粘合剂，其中硅烷偶联剂与树脂具有改善的相容性，并在与具有羟基的基体树脂的粘接强度和相互作用方面表现出卓越的性能，同时还能够具有初始可再加工性，并在高温或高温高湿条件下具有高粘合力。
• CURABLE RESIN COMPOSITION, COMPOSITION FOR FORMING SOLDER RESIST, DRY FILM AND PRINTED WIRING BOARD, AND LAMINATE AND PROCESS FOR PREPARING THE SAME
  申请人：TAIYO INK MFG. CO., LTD.

  公开号：US20150240071A1

  公开（公告）日：2015-08-27

  The present invention provides a curable resin composition that can provide a cured material excellent in insulation reliability while maintaining adhesiveness and provide a composition for forming a solder resist, a dry film and a printed wiring board, a laminate having a resin insulating layer excellent in insulation reliability while maintaining adhesiveness, a dry film for forming this and a process for preparing a laminate using the dry film. The curable resin composition contains (A) an imidazole-isocyanate adduct, (B) a carboxyl group-containing resin and (C) a thermosetting resin. The above laminate has a substrate and a plurality of resin insulating layers formed on the substrate, in which one of the plural resin insulating layers in contact with the substrate is a layer formed of the curable resin composition.

  本发明提供了一种可固化树脂组合物，可以在保持粘附性的同时提供优异的绝缘可靠性的固化材料，并提供用于形成焊盘阻焊层、干膜和印制电路板的组合物、具有优异的绝缘可靠性和粘附性的树脂绝缘层的层压板、用于形成该层压板的干膜以及制备层压板的方法。可固化树脂组合物包含（A）咪唑-异氰酸酯加合物，（B）含有羧基的树脂和（C）热固性树脂。上述层压板具有基板和形成在基板上的多个树脂绝缘层，其中与基板接触的众多树脂绝缘层之一是由可固化树脂组合物形成的层。
• Polymodal conjugated diolefin vinyl aromate rubber composition
  申请人：JSR Corporation

  公开号：EP1000970A1

  公开（公告）日：2000-05-17

  A conjugated diolefin copolymer rubber and a rubber composition which can produce vulcanized products exhibiting well-balanced improved properties such as wet skid properties, low hysteresis loss properties, abrasion resistance, and breaking strength irrespective of the types and combinations of fillers to be added, and is useful as a tread material for low fuel consumption tires, large tires, and high performance tires. A conjugated diolefin copolymer rubber is prepared by the copolymerization of a conjugated diolefin and a vinyl aromatic compound, and (1) has a content of the bonded vinyl aromatic compound of 5-50 wt%, (2) contains 0.01-5.0 mmol of an alkoxysilyl group having substantially non-hydrolyzable Si-O-R bond (wherein R indicates a hydrocarbon group having 4-20 carbon atoms) and 0.01-2.0 mmol of a tin-carbon bond for 100 g of the copolymer rubber, and (3) has a polymodal-type molecular weight distribution.

  一种共轭二烯烃共聚物橡胶和一种橡胶组合物，无论添加填料的类型和组合如何，都能生产出均衡改善性能的硫化产品，如湿滑性能、低滞后损失性能、耐磨性和断裂强度，可用作低油耗轮胎、大型轮胎和高性能轮胎的胎面材料。共轭二烯烃共聚橡胶由共轭二烯烃和乙烯基芳香化合物共聚制备而成，(1) 键合乙烯基芳香化合物的含量为 5-50 wt%，(2) 含有 0.01-5.0毫摩尔具有基本上不可水解的Si-O-R键的烷氧基硅基（其中R表示具有4-20个碳原子的烃基）和0.01-2.0毫摩尔的锡-碳键的共聚橡胶，以及（3）具有多模态型分子量分布。
• PHOTOCURABLE/THERMOSETTING RESIN COMPOSITION, CURED PRODUCT AND PRINTED WIRING BOARD
  申请人：Taiyo Ink MFG. CO., LTD.

  公开号：EP2083019A1

  公开（公告）日：2009-07-29

  The present invention provides a photocurable and thermosetting resin composition having excellent surface curability and deep curability, allowing pattern formation with a laser beam having a wavelength of 350 to 410 nm, and being useful as a solder resist for laser direct imaging, the composition including a carboxylic resin (A), an oxime ester-based photopolymerization initiator (B) such as 2-(acetyloxyiminomethyl)thioxanthene-9-one, and another photopolymerization initiator than (B) such as 2,4,6-trimethylbenzoyl-diphenyl-phosphine oxide, and a sulfur compound (E) such as 2-mercaptobenzothiazole.

  本发明提供了一种光固化热固性树脂组合物，该组合物具有优异的表面固化性和深度固化性，可以用波长为 350 至 410 纳米的激光束形成图案，并可用作激光直接成像的阻焊材料、该组合物包括羧基树脂（A）、肟酯类光聚合引发剂（B）（如 2-(乙酰氧基亚氨基甲基)硫杂蒽-9-酮）、另一种光聚合引发剂（B）（如 2,4,6-三甲基苯甲酰基二苯基氧化膦）和硫化合物（E）（如 2-巯基苯并噻唑）。