| 253684-06-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• CAS: 253684-06-9
• 化学式: C₁₁H₁₄N
• 分子量: 160.239
• InChiKey: WYYNEDSGEACLHC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.2
• 重原子数：
  12
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.36
• 拓扑面积：
  3.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  生成 1-(1,2-Diphenyl-2-pyrrolidin-1-ylethyl)pyrrolidine
  参考文献：
  名称：

  EPR Studies on the SmI₂-Promoted Coupling of N-(N‘,N‘-Dialkylaminoalkyl)benzotriazoles

  摘要：

  [GRAPHICS]Radicals generated in the Sml(2)-promoted coupling of N-(N',N'-dialkylaminoalkyl)benzotriazoles 1 have been detected using the EPR spin-trapping technique, Single electron transfer (SET) between 1 and Sml(2) is discussed as a mechanism for the formation of the radicals.

  DOI：

  10.1021/ol9902733
• 作为产物：
  描述：

  N-(α-benzotriazolylbenzyl)pyrrolidine 在 samarium diiodide 作用下， 以 四氢呋喃 为溶剂， 生成
  参考文献：
  名称：

  EPR Studies on the SmI₂-Promoted Coupling of N-(N‘,N‘-Dialkylaminoalkyl)benzotriazoles

  摘要：

  [GRAPHICS]Radicals generated in the Sml(2)-promoted coupling of N-(N',N'-dialkylaminoalkyl)benzotriazoles 1 have been detected using the EPR spin-trapping technique, Single electron transfer (SET) between 1 and Sml(2) is discussed as a mechanism for the formation of the radicals.

  DOI：

  10.1021/ol9902733

文献信息

• EPR Studies on the SmI₂-Promoted Coupling of <i>N</i>-(<i>N</i>‘,<i>N</i>‘-Dialkylaminoalkyl)benzotriazoles
  作者：Alan R. Katritzky、Hai-Ying He、Guofang Qiu、Peter J. Bratt、Sidney H. Parrish、Alexander Angerhofer

  DOI：10.1021/ol9902733

  日期：1999.12.1

  [GRAPHICS]Radicals generated in the Sml(2)-promoted coupling of N-(N',N'-dialkylaminoalkyl)benzotriazoles 1 have been detected using the EPR spin-trapping technique, Single electron transfer (SET) between 1 and Sml(2) is discussed as a mechanism for the formation of the radicals.