[Cu(1,4-diazacycloheptane)2(N3)]ClO4 | 444018-29-5

• 分子结构分类: 有机化合物 - 有机氧化合物 - 有机含氧阴离子化合物
• 英文名称: [Cu(1,4-diazacycloheptane)2(N3)]ClO4
• 英文别名: [Cu(dach)2(N3)]ClO4
• CAS: 444018-29-5
• 化学式: C₁₀H₂₄CuN₇*ClO₄
• 分子量: 405.344
• InChiKey: MYBMPWUPLQMZBI-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  copper(II) perchlorate hexahydrate 、 高哌嗪 、 sodium azide 以 甲醇 、 水 为溶剂， 生成 [Cu(1,4-diazacycloheptane)2(N3)]ClO4
  参考文献：
  名称：

  Synthesis, characterisation and structural studies of [Cu(dach)(μ-NCS)(NCS)]n and [Cu(dach)2(N3)]ClO4 (dach=1,4-diazacycloheptane)

  摘要：

  A new singly bridging complex [Cu(dach)(mu-NCS)(NCS)](n) (dach = 1,4-diazacycloheptane) has been synthesised and its crystal structure determined. There are many examples of double NCS bridged polymeric chains, but fewer singly bridged ones. IR, ESR and temperature variable magnetic studies are described but no magnetic interaction was found between the copper centres, [Cu(dach)(2)(N-3)]ClO4 has also been characterised by IR, ESR spectra and magnetic studies. The crystal structure determination shows that it is a penta-coordinated monomeric species with an axially coordinated azide linked to the perchlorate counterion by hydrogen bonding. (C) 2002 Published by Elsevier Science B.V.

  DOI：

  10.1016/s0020-1693(01)00822-2