N-(4-methylphenyl)anthracen-9-amine | 15424-39-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: N-(4-methylphenyl)anthracen-9-amine
• 英文别名: N-(p-tolyl)anthracene-9-amine；9-<4-Toluidino>-anthracen；9-p-Tolylamino-anthracen；[9]anthryl-p-tolyl-amine；N-(10H-Anthryliden-(9))-p-toluidin；N-(Anthryl-(9))-p-toluidin；9-p-Toluidino-anthracen；Anthron-p-tolylimin；9-p-Toluidinoanthracene
• CAS: 15424-39-2
• 化学式: C₂₁H₁₇N
• 分子量: 283.373
• InChiKey: OMRMKWZAJLUPFO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.3
• 重原子数：
  22
• 可旋转键数：
  2
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.05
• 拓扑面积：
  12
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  N-(4-methylphenyl)anthracen-9-amine 在 air 作用下， 生成 N--anthrachinon-monoimin
  参考文献：
  名称：

  Rigaudy; Cauquis, Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1956, vol. 242, p. 2964

  摘要：

  DOI：
• 作为产物：
  描述：

  蒽酮 、 乙烷,三氯氟- 生成 N-(4-methylphenyl)anthracen-9-amine
  参考文献：
  名称：

  Rigaudy; Cauquis, Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1956, vol. 242, p. 2964

  摘要：

  DOI：

文献信息

• N‐Heterocyclic Olefin‐Ligated Palladium(II) Complexes as Pre‐Catalysts for Buchwald–Hartwig Aminations
  作者：Ian C. Watson、André Schumann、Haoyang Yu、Emma C. Davy、Robert McDonald、Michael J. Ferguson、Christian Hering‐Junghans、Eric Rivard

  DOI：10.1002/chem.201901376

  日期：2019.7.22

  New N‐heterocyclic olefins (NHOs) are described with functionalization on the ligand heterocyclic backbone and terminal alkylidene positions. Various PdII–NHO complexes have been formed and their use as pre‐catalysts in Buchwald–Hartwig aminations was explored. The most active system for catalytic C−N bond formation between hindered arylamine and arylhalide substrates was accessed by combining a backbone

  描述了在配体杂环主链和末端亚烷基位置有官能化的新型N-杂环烯烃（NHO）。已经形成了各种Pd II- NHO络合物，并探索了它们在布赫瓦尔德-哈特维希胺化中作为预催化剂的用途。受阻的芳基胺和芳基卤化物底物之间形成催化C-N键的活性最高的系统是通过在NaO t Bu为碱的情况下将主链甲基化的NHO与[Pd（肉桂基）Cl] 2结合而获得的。在这些活性系统中，证据表明催化作用是由胶态钯金属介导的，这突出了与常用的N杂环卡宾配体相比，NHO具有不同的配位能力。
• Palladium-Catalyzed Amination of Aryl Sulfides with Anilines
  作者：Tomohiro Sugahara、Kei Murakami、Hideki Yorimitsu、Atsuhiro Osuka

  DOI：10.1002/anie.201404355

  日期：2014.8.25

  A combination of a palladium–NHC catalyst and potassium hexamethyldisilazide enables the amination of aryl sulfides with anilines to afford a wide variety of diarylamines. The reaction conditions are versatile enough for the reaction of even bulky ortho‐substituted aryl sulfides. This amination can be applied to the modular synthesis of N‐aryl carbazoles from the corresponding ortho‐bromothioanisoles

  钯-NHC催化剂和六甲基二硅氮合钾的组合能够使芳基硫化物与苯胺发生胺化反应，从而提供多种二芳基胺。该反应条件足够通用，甚至可以用于庞大的邻位取代的芳基硫化物的反应。该胺化反应可用于由相应的邻-溴硫代苯甲醚合成N-芳基咔唑的模块。当芳基亚砜经历扩展的Pummerer反应以提供邻位取代的芳基硫化物时，Pummerer产品成为有用的底物，可用于氨化反应，最终完成2-苯胺基苯并噻吩和吲哚的高效合成，作为扩展效用原理的证明Pummerer反应/胺化级联。
• ANILINE DERIVATIVES AND USES THEREOF
  申请人：NISSAN CHEMICAL INDUSTRIES, LTD.

  公开号：US20160301011A1

  公开（公告）日：2016-10-13

  Aniline derivatives such as those represented by the formula shown, for example, have good solubility with respect to organic solvents, and are able to provide an organic electroluminescent element having excellent luminance characteristics when a thin film containing said aniline derivatives is used as a charge transporting substance in a hole injection layer. (In the formula, DPA represents a diphenylamino group.)
• CHARGE TRANSPORT MATERIAL
  申请人：NISSAN CHEMICAL INDUSTRIES, LTD.

  公开号：US20170213986A1

  公开（公告）日：2017-07-27

  A charge transport material containing a charge transport substance that is composed of a compound represented by formula (1) and another charge transport substance that is composed of a charge transport compound having a molecular weight of 200-9,000 exhibits good solubility in an organic solvent. A charge transport varnish, from which a charge transport thin film having excellent charge transport properties, flatness and uniformity is formed with good reproducibility, is able to be prepared by dissolving the above-described charge transport material in an organic solvent.