| 220782-98-9

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• CAS: 220782-98-9
• 化学式: C₇H₁₁N₂NaO₈Pd
• 分子量: 380.583
• InChiKey: SRUWONRKICSRSX-UHFFFAOYSA-K

反应信息

• 作为产物：
  描述：

  sodium tetrachloropalladate(II) 、 diethyl N,N'-trimethylenebis(oxamate) 在 NaOH 作用下， 以 水 为溶剂， 生成
  参考文献：
  名称：

  Synthesis and crystal structure of Na[Pd(Hpba)]·2H2O [H4pba=1,3-propylenebis(oxamic acid)]. The first bis(oxamato)palladium(II) complex and an unexpected trideprotonated form of the ligand

  摘要：

  The complex of formula Na[Pd(Hpba)]. 2H(2)O, in which H(4)pba is 1,3-propylenebis(oxamic acid), was obtained by reaction of the diethyl ester of the 1,3-propylenebis(oxamic acid) and Na2PdCl4 in basic conditions. The X-ray structure consists of [N,N'-(1,3-propanediyl)bis(oxamato-N,O)]palladate(II) dihydrate anions, sodium cations and water molecules coordinated to the sodium cations, linked together to give rise to polymeric chains [Na(H2O)(2)Pd(Hpba)](n). Within the [Pd(Hpba)](-) anions, Pd(II) atom occupies the N2O2 inner-site of the ligand displaying a distorted square-planar coordination. Interestingly, the Ligand coordinates to Pd(II) in an unexpected trideprotonated fashion; the remaining hydrogen atom being located on an amide oxygen atom. (C) 1999 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0020-1693(98)00298-9