| 1410808-94-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯
• CAS: 1410808-94-4
• 化学式: C₃₀H₄₂CoN₆O₄
• 分子量: 609.694
• InChiKey: UDLVTZYNOFJPDG-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  3,5-二甲基吡唑 、 Co₂(μ₂-OCO^tBu)₄(OCO^tBu)₂(μ₂-H₂O)(2,2’-bpy)₂ 反应 1.0h， 以74%的产率得到
  参考文献：
  名称：

  Interaction of 3,5-dimethylpyrazole with cobalt(II) carboxylates containing coordinated 1,10-phenanthroline or 2,2′-dipyridyl

  摘要：

  The reaction of Co-3(mu-OOCBu (t) )(6)(NEt3)(2) with 1,10-phenanthroline or 2,2'-dipyridyl in benzene at room temperature yields L2Co2(mu-OH2)(mu-OOCBu (t) )(4) complexes (L-2 = Phen (1a) and Dipy (1b)). The reaction of n1a (1b) with 3,5-dimethylpyrazole gives a mixture of L2Co(Hdmpz)(2)(OOCBu (t) )(2) complexes (2a, 2b) and L2Co(Hdmpz)(OOCBu (t) )(2) (3a, 3b), and their yield is determined by the ratio of the initial reagents. As distinct from pivalates, for cobalt(II) phenanthroline-benzoate, only the (Phen)Co(Hdmpz)(2)(OOCPh)(2) complex (4) has been isolated. The structures of the synthesized compounds have been determined by X-ray crystallography.

  DOI：

  10.1134/s0036023612090215