oct-3t-ene-1,2-diol | 52812-52-9

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: oct-3t-ene-1,2-diol
• 英文别名: 3-octene-1,2-diol；trans-3-Octen-1,2-diol；(E)-oct-3-ene-1,2-diol
• CAS: 52812-52-9
• 化学式: C₈H₁₆O₂
• 分子量: 144.214
• InChiKey: XTGAENOYYJUUMF-AATRIKPKSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.3
• 重原子数：
  10
• 可旋转键数：
  5
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.75
• 拓扑面积：
  40.5
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  4-hex-1-en-t-yl-2,2-dimethyl-[1,3]dioxolane 在 酒石酸 作用下， 生成 oct-3t-ene-1,2-diol
  参考文献：
  名称：

  Lalande,R. et al., Comptes Rendus des Seances de l'Academie des Sciences, Serie C: Sciences Chimiques, 1974, vol. 278, p. 963 - 965

  摘要：

  DOI：

文献信息

• Synthesis of enantiopure chloroalcohols by enzymatic kinetic resolution
  作者：Robert M. Haak、Chiara Tarabiono、Dick B. Janssen、Adriaan J. Minnaard、Johannes G. de Vries、Ben L. Feringa

  DOI：10.1039/b613937j

  日期：——

  3-Alkenyl and heteroaryl chloroalcohols have been obtained in excellent enantiomeric excess (>99%) by enzymatic kinetic resolution using the haloalcohol dehalogenase HheC. Yields were close to the theoretical maximum for all substrates employed. Furthermore, the applicability of this methodology on multigram scale has been established.

  通过使用卤醇脱卤酶HheC进行酶促动力学拆分，成功获得了具有优异对映体过剩（>99%）的3-烯基和杂芳基氯醇。所有使用底物的产率均接近理论最大值。此外，该方法在大规模多克重应用中的适用性也得到了验证。
• Alcohol production
  申请人：Phillips Petroleum

  公开号：US04065511A1

  公开（公告）日：1977-12-27

  Selected organic peroxides are converted to the corresponding alcohols when contacted with a triorganophosphine in a reaction medium comprising water and an organic solvent miscible with water. In one embodiment, diene polyperoxides are converted to the novel diols.

  在含有水和可与水混溶的有机溶剂的反应介质中，当选择性的有机过氧化物与三有机膦接触时，它们会被转化为相应的醇。在一个实施例中，二烯基聚过氧化物被转化为新型二元醇。
• Concentrated, stable fabric softening composition
  申请人：——

  公开号：US20030153483A1

  公开（公告）日：2003-08-14

  Principal solvents, especially mono-ol and diol principal solvents, having a ClogP of from about 0.15 to about 0.64, preferably from about 0.25 to about 0.62, and more preferably from about 0.40 to about 0.60, are disclosed that have the ability to make clear aqueous fabric softener compositions containing relatively high concentrations of fabric softener actives having ester linkages in their long, hydrophobic chains. The fabric softener actives are either unsaturated, or have intermediate length chains (˜C 12-14 ) and the said principal solvents are used at levels of less than about 40%. Other solvents may be present. Some of the said principal solvents are novel compounds and/or novel mixtures. Premixes of the fabric softening actives, the principal solvents, and, optionally, other solvents are useful in the preparation of complete formulations by obviating/limiting the need for heating.

  本发明涉及主要溶剂，特别是具有从约0.15到约0.64的ClogP值的单醇和二醇主要溶剂，优选从约0.25到约0.62，更优选从约0.40到约0.60，具有使含有长的亲水性链中的酯键的织物柔软剂活性成分相对高浓度的清澈水性织物柔软剂组合物的能力。织物柔软剂活性成分可以是不饱和的，也可以具有中等长度的链（约C12-14），所述主要溶剂的使用水平低于约40％。其他溶剂可能也存在。其中一些主要溶剂是新化合物和/或新混合物。织物柔软剂活性成分、主要溶剂和可选的其他溶剂的预混物可用于制备完整配方，从而避免/限制加热的需要。
• DESOXYAZAPHOSPHOLIPID DERIVATIVES HAVING INHIBITING ACTIVITY ON PHOSPHOLIPASE A2
  申请人：LABORATORIOS MENARINI S.A.

  公开号：EP0701561A1

  公开（公告）日：1996-03-20
• CONCENTRATED, STABLE FABRIC SOFTENING COMPOSITION
  申请人：THE PROCTER & GAMBLE COMPANY

  公开号：EP0842250A1

  公开（公告）日：1998-05-20