Malonic acid mono-[3,5,6,7,9,13,15,17,19-nonahydroxy-14,16,18-trimethyl-1-(2,4,6,7-tetrahydroxy-5-methyl-heptyl)-nonadecyl] ester | 81875-48-1

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: Malonic acid mono-[3,5,6,7,9,13,15,17,19-nonahydroxy-14,16,18-trimethyl-1-(2,4,6,7-tetrahydroxy-5-methyl-heptyl)-nonadecyl] ester
• CAS: 81875-48-1
• 化学式: C₃₃H₆₄O₁₇
• 分子量: 732.861
• InChiKey: LBSVCGBNRNSWIU-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  Malonic acid mono-[3,5,6,7,9,13,15,17,19-nonahydroxy-14,16,18-trimethyl-1-(2,4,6,7-tetrahydroxy-5-methyl-heptyl)-nonadecyl] ester 在 sodium hydroxide 作用下， 生成 3,21,23,25-Tetramethyl-hexacosane-1,2,4,6,8,10,12,13,14,16,20,22,24,26-tetradecaol
  参考文献：
  名称：

  Structure of scopafungin, a potent nonpolyene antifungal antibiotic

  摘要：

  DOI：

  10.1021/ja00379a015
• 作为产物：
  描述：

  Malonic acid mono-{3,5,7-trihydroxy-6-methyl-8-oxo-1-[4,5,6-trihydroxy-6-(2,6,8,10-tetrahydroxy-7,9,11-trimethyl-12-oxo-dodecyl)-tetrahydro-pyran-2-ylmethyl]-octyl} ester 在 sodium tetrahydroborate 作用下， 以 乙醇 为溶剂， 反应 2.0h， 以150 mg的产率得到Malonic acid mono-[3,5,6,7,9,13,15,17,19-nonahydroxy-14,16,18-trimethyl-1-(2,4,6,7-tetrahydroxy-5-methyl-heptyl)-nonadecyl] ester
  参考文献：
  名称：

  Structure of scopafungin, a potent nonpolyene antifungal antibiotic

  摘要：

  DOI：

  10.1021/ja00379a015