N-xylylbenzimidoylchloride | 60065-94-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N-xylylbenzimidoylchloride
• 英文别名: N-(2,4-dimethyl-phenyl)-benzimidoyl chloride；N-(2,4-Dimethyl-phenyl)-benzimidoylchlorid；N-(2.4-Dimethyl-phenyl)-benzimidchlorid；N-(2,4-Dimethylphenyl)benzenecarboximidoyl chloride
• CAS: 60065-94-3
• 化学式: C₁₅H₁₄ClN
• 分子量: 243.736
• InChiKey: VVJYKAGCYJQWCO-UHFFFAOYSA-N

物化性质

• 沸点：
  373.5±52.0 °C(Predicted)
• 密度：
  1.06±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5
• 重原子数：
  17
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.13
• 拓扑面积：
  12.4
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  N-xylylbenzimidoylchloride 在 sodium hydroxide 作用下， 生成 2,4-dimethylacridone
  参考文献：
  名称：

  411.二苯胺的某些衍生物以及N-芳基邻氨基苯甲酸和cri烯的新合成

  摘要：

  DOI：

  10.1039/jr9370001954
• 作为产物：
  描述：

  N-(2,4-二甲基苯基)苯甲酰胺 在 五氯化磷 作用下， 生成 N-xylylbenzimidoylchloride
  参考文献：
  名称：

  Gibson; Johnson, Journal of the Chemical Society, 1929, p. 2748

  摘要：

  DOI：

文献信息

• 3H-1,3,4-Benzotriazepines from (N-arylbenzimidoyl)-5-dimethylaminotetrazoles: 1,7-vs. 1,5-cyclisation of extended dipolar nitrile imines
  作者：Gerhard V. Boyd、John Cobb、Peter F. Lindley、John C. Mitchell、George A. Nicolaou

  DOI：10.1039/c39870000099

  日期：——

  Thermolysis of both 1- and 2-N-arylbenzimidoyl-5-dimethylaminotetrazoles [(7) or (8)] generates nitrile imines (9), which cyclise to yield either 1,2,4-triazoles (10) or 3H-1,3,4-benzotriazepines (12), depending on the nature of the N-aryl group and on conditions.

  两个1-热分解和2- Ñ -arylbenzimidoyl -5- dimethylaminotetrazoles [（7）或（8）]产生的腈亚胺（9），得到环化其中任一1,2,4-三唑（10）或3 ħ - 1,3,4-苯并三氮杂卓（12），取决于N-芳基的性质和条件。
• Phosphorus Can Also Be a “Photocopy”
  作者：Marlena P. Washington、Vittal B. Gudimetla、Feng L. Laughlin、Nihal Deligonul、Susan He、John L. Payton、M. Cather Simpson、John D. Protasiewicz

  DOI：10.1021/ja1009426

  日期：2010.4.7

  The syntheses of benzoxaphospholes and new benzobisoxaphospholes that display blue fluorescence are presented. The latter compounds were accessed by the use of a new precursor, 2,5-diphosphinohydroquinone. The new compounds were fully characterized, including a structural study of 2,6-tert-butylbenzo[1,2-d;4,5-d']bisoxaphosphole. Quantum yields for photoluminescence were determined for a series of compounds. These materials feature bona fide P=C p-p pi bonds suitable for conjugated materials having phosphorus as a participatory atom and can thus "photocopy" the properties of other conjugated organic molecules.
• 920. A new synthesis of 2 : 3 : 5 : 6-substituted 4-pyrimidones
  作者：Benjamin Staskun、Henry Stephen

  DOI：10.1039/jr9560004708

  日期：——
• Familial Aggregation of 7-Year Changes in Musculoskeletal Fitness
  作者：P. T. Katzmarzyk、N. Gledhill、L. Perusse、C. Bouchard

  DOI：10.1093/gerona/56.12.b497

  日期：2001.12.1

  The purpose of this study was to determine the degree of familial resemblance in baseline and 7-year changes in musculoskeletal fitness. Data front the 1981 Canada Fitness Survey and the Campbell's Survey 7-year follow-up were used. The sample consisted of 1264 people (635 males and 629 females) between the ages of 7 and 69 years for whom measurements of musculoskeletal fitness were available at baseline. A subsample of 834 people had measurements at both baseline and 7-year follow-up. Sit-and-reach trunk flexibility, number of push-ups without time limit, number of sit-ups in 60 seconds, and hand-grip strength were used as indicators of musculoskeletal fitness. The data were adjusted for the effects of age and body mass index (and baseline level of the variable for changes) by using regression procedures, and they were standardized to zero mean and unit variance within each of the four sex-by-generation groups (fathers, mothers, sons, and daughters), Familial correlation models were fitted to the data by using the computer software SEGPATH. The results indicate significant familial resemblance for all indicators of musculoskeletal fitness for baseline measures and 7-year changes. The heritabilities, or the percentages of the total variance attributable to heredity, were 64% for trunk flexibility, 37% for push-ups, 59% for sit-ups, and 48% for grip strength. Similarly, heritabilities for the change scores were 48% for trunk flexibility, 52% for push-ups, 41% for sit-ups, and 32% for grip strength. The results suggest that familial, and perhaps genetic, factors are important in explaining the variance in musculoskeletal fitness not only cross-sectionally but also for changes over time.
• 2-Aryl-3-acetyl-4(1H)-quinolones¹
  作者：P. C. Anderson、B. Staskun

  DOI：10.1021/jo01020a034

  日期：1965.9