mono(myristato)mono(thioacetato)cobalt(II) | 504395-61-3

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: mono(myristato)mono(thioacetato)cobalt(II)
• CAS: 504395-61-3
• 化学式: C₂H₃OS*C₁₄H₂₇O₂*Co
• 分子量: 361.472
• InChiKey: SFZZEZZVBDKQFE-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  3.51
• 重原子数：
  21.0
• 可旋转键数：
  12.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.88
• 拓扑面积：
  57.2
• 氢给体数：
  0.0
• 氢受体数：
  4.0

反应信息

• 作为产物：
  描述：

  bis(thioacetato)cobalt(II) 、 肉豆蔻酸 以 甲苯 为溶剂， 以61%的产率得到mono(myristato)mono(thioacetato)cobalt(II)
  参考文献：
  名称：

  SYNTHESIS AND CHARACTERIZATION OF SOME TRINUCLEAR COBALT(II) THIOCARBO XYLATES

  摘要：

  Some cobalt(II) complexes of thiocarboxylic acids with the general composition Co(SOCR')(2) and Co(SOCR')(OOCR) [where R = C13H27, C15H31 or C17H35 and R' = CH3 or C6H5] have been. synthesized by substitution reactions and characterized by elemental analyses, spectral, studies and magnetic moment measurements. The electrical conductance data indicate that (Co(SOCCH3)(2) is a 1:2 electrolyte while the other complexes are non-electrolytes. IR spectra show the presence of bidentate and bridging modes of coordination for carboxylate and thiocarboxylate anions, respectively. Electronic spectral data and magnetic moment values indicate an octahedral environment around cobalt(II). The plausible structure for the trimeric species has been proposed on the basis of the physico-chemical studies. Thermoanalytical data indicate the complexes are stable upto 175 degreesC, above which decomposition starts.

  DOI：

  10.1081/sim-120016473