4-ferrocenylphenyl-4'-octyloxy-4-biphenylcarboxylate | 516479-02-0

• 英文名称: 4-ferrocenylphenyl-4'-octyloxy-4-biphenylcarboxylate
• CAS: 516479-02-0
• 化学式: C₃₇H₃₈FeO₃
• 分子量: 586.554
• InChiKey: PYZHDHJKIXZBJY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  ferrocenylphenol 、 4-正辛氧基联苯-4-甲酸 在 4-dimethylaminopyridine 、 dicyclohexylcarbodiimide 作用下， 以 二氯甲烷 为溶剂， 生成 4-ferrocenylphenyl-4'-octyloxy-4-biphenylcarboxylate
  参考文献：
  名称：

  The synthesis and liquid crystal behaviour of monosubstituted ferrocenomesogens

  摘要：

  The synthesis and characterization of several new series of monosubstituted ferrocenyl-containing liquid crystals has been achieved. The results indicate that a terminal ferrocenyl group can promote stabilization of a nematic liquid crystal state. At least three phenyl rings are required in the molecular core in order to provide nematic properties and addition of a fourth ring substantially enhances it. Bulky lateral substituents or the introduction of linker groups that introduce kinks inhibit liquid crystal phase formation. Short highly polarising terminal groups or terminal groups that support hydrogen bonding support liquid crystal behaviour. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(02)02044-2