2,2'-methylenebis[6-(5-chloro-2H-benzotriazole-2-yl)-4-(2-hydroxyethyl)phenol] | 196516-62-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2,2'-methylenebis[6-(5-chloro-2H-benzotriazole-2-yl)-4-(2-hydroxyethyl)phenol]
• 英文别名: 2-(5-chlorobenzotriazol-2-yl)-6-[[3-(5-chlorobenzotriazol-2-yl)-2-hydroxy-5-(2-hydroxyethyl)phenyl]methyl]-4-(2-hydroxyethyl)phenol
• CAS: 196516-62-8
• 化学式: C₂₉H₂₄Cl₂N₆O₄
• 分子量: 591.453
• InChiKey: MSBYJOHVJGSWQZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.4
• 重原子数：
  41
• 可旋转键数：
  8
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.17
• 拓扑面积：
  142
• 氢给体数：
  4
• 氢受体数：
  8

反应信息

• 作为产物：
  描述：

  2-(5-chloro-2H-benzotriazole-2-yl)-4-(2-hydroxyethyl)-6-(N,N-diethylaminomethyl)phenol 、 、 2-(5-chloro-2H-benzotriazole-2-yl)-4-(2-hydroxyethyl)phenol 、 甲醇 、 sodium methylate 在 氮 作用下， 以 邻二甲苯 为溶剂， 反应 10.0h， 以giving 30.8 g of 2,2'-methylenebis[6-(5-chloro-2H-benzotriazole-2-yl)-4-(2-hydroxyethyl)phenol] as pale yellow crystals (yield 55.0%, purity 99.0%)的产率得到2,2'-methylenebis[6-(5-chloro-2H-benzotriazole-2-yl)-4-(2-hydroxyethyl)phenol]
  参考文献：
  名称：

  Bisbenzotriazolylphenol compound

  摘要：

  本发明的目的是提供一种具有紫外线吸收效果的新型双苯并三氮唑基酚类化合物。该发明的双苯并三氮唑基酚类化合物由下式表示：##STR1##其中，A是直接键或表示C.sub.1-6烷基、--C(CH.sub.3).sub.2--基团、--C(C.sub.2H.sub.5)(CH.sub.3)--基团、--O--基团或--NH--基团；R.sup.1和R.sup.3相同或不同，且分别表示氢原子、C.sub.1-4烷基、芳基、C.sub.1-4烷氧基或卤素原子；R.sup.2和R.sup.4相同或不同，且分别表示羟基或C.sub.1-12直链或支链羟基烷基。

  公开号：

  US05922882A1

文献信息

• BISBENZOTRIAZOLYLPHENOLS
  申请人：OTSUKA KAGAKU KABUSHIKI KAISHA

  公开号：EP0855393A1

  公开（公告）日：1998-07-29

  An object of the present invention is to provide a novel bisbenzotriazolylphenol compound having a UV absorving effect. The bisbenzotriazolylphenol compound of the invention is represented by the formula wherein A is a direct bond or represents a C1-6 alkylene group, a -C(CH3)2- group, a -C(C2H5)(CH3)- group, a -O- group or a -NH- group, R1 and R3 are the same or different and each represent a hydrogen atom, a C1-4 alkyl group, an aryl group, a C1-4 alkoxy group or a halogen atom, and R2 and R4 are the same or different and each represent a hydroxyl group or a C1-12 straight- or branched-chain hydroxyalkyl group.

  本发明的目的是提供一种具有紫外线吸收效果的新型双苯并三唑基苯酚化合物。本发明的双苯并三唑基苯酚化合物由式表示 其中 A 是直接键或代表 C1-6 亚烷基、-C(CH3)2- 基团、-C(C2H5)( )- 基团、-O- 基团或-NH- 基团，R1 和 R3 相同或不同，各自代表氢原子、C1-4 烷基、芳基、C1-4 烷氧基或卤原子，R2 和 R4 相同或不同，各自代表羟基或 C1-12 直链或支链羟烷基。
• SEALING FILM FOR SOLAR CELL AND SOLAR CELL USING THE SAME
  申请人：Bridgestone Corporation

  公开号：EP2216828A1

  公开（公告）日：2010-08-11

  A sealing film for a solar cell is provided, which has excellent ultraviolet resistance. The sealing film for a solar cell according to the present invention includes ethylene-vinyl acetate copolymer; an organic peroxide; a benzotriazole-based ultraviolet absorber; and a hindered amine-based light stabilizer. The content of the benzotriazole-based ultraviolet stabilizer is in the range of 0.01 to 0.3 parts by weight, based on 100 parts by weight of ethylene-vinyl acetate copolymer. Further, the content of the hindered amine-based light stabilizer is in the range of 0.01 to 2 parts by weight, based on 100 parts by weight of ethylene-vinyl acetate copolymer.

  本发明提供了一种太阳能电池密封膜，它具有优异的抗紫外线性能。根据本发明，太阳能电池密封膜包括乙烯-醋酸乙烯共聚物、有机过氧化物、苯并三唑类紫外线吸收剂和受阻胺类光稳定剂。苯并三唑类紫外线稳定剂的含量范围为 0.01 至 0.3 重量份（以 100 重量份乙烯-醋酸乙烯共聚物为基准）。此外，以 100 份乙烯-醋酸乙烯共聚物的重量为基准，受阻胺类光稳定剂的含量在 0.01 至 2 份的重量范围内。
• SEALING FILM FOR SOLAR CELL
  申请人：Adeka Corporation

  公开号：EP2511958A1

  公开（公告）日：2012-10-17

  Provided is a sealing film for a solar battery which has excellent light resistance and heat resistance by preventing yellowing due to the influence of light or heat. The sealing film for a solar battery, in which 0.05-10 parts by weight of a hindered amine compound having a substructure represented by the following general formula (I): (wherein R1, R2, R3, and R4 each independently represent C1-C4 lower alkyl; and R represents hydrogen, C1-C18 straight- or branched-chain alkyl which may be substituted by hydroxy, or C5-C8 cycloalkyl) based on 100 parts by weight of an ethylene-vinyl acetate copolymer is blended.

  本发明提供了一种太阳能电池密封膜，它具有优异的耐光性和耐热性，可防止因光或热的影响而变黄。 该太阳能电池密封膜中含有 0.05-10 重量份的受阻胺化合物，其子结构由以下通式（I）表示： (其中 R1、R2、R3 和 R4 各自独立地代表 C1-C4 低级烷基；R 代表氢、C1-C18 直链或支链烷基（可被羟基取代）或 C5-C8 环烷基），以 100 份（重量）乙烯-醋酸乙烯共聚物为基准。
• SEALING MATERIAL COMPOSITION FOR SOLAR CELLS, SEALING MATERIAL LAYER FOR SOLAR CELLS USING SAME, AND SOLAR CELL MODULE
  申请人：Nitto Denko Corporation

  公开号：EP3193377A1

  公开（公告）日：2017-07-19

  Provided are a encapsulant composition that is for solar cells and can reduce the time required for a lamination process and improve light stability and resistance to moisture and heat, and a solar cell encapsulant layer and a solar cell module, each produced with the composition, wherein the composition includes an ethylenic copolymer and an organic peroxide having a peroxyester structure represented by formula (1) or (2) wherein R1, R2, R3, and R4 each independently represent an optionally substituted alkyl group of 1 to 18 carbon atoms or an optionally substituted aryl group of 5 to 18 carbon atoms.

  提供了一种用于太阳能电池的封装剂组合物，该组合物可以缩短层压工艺所需的时间，并提高光稳定性和耐湿耐热性，还提供了一种太阳能电池封装层和太阳能电池组件，每种太阳能电池组件都是用该组合物生产的，其中该组合物包括乙烯共聚物和具有由式（1）或（2）表示的过氧化酯结构的有机过氧化物。 其中 R1、R2、R3 和 R4 各自独立地代表 1 至 18 个碳原子的任选取代的烷基或 5 至 18 个碳原子的任选取代的芳基。
• NEAR-INFRARED-SHIELDING ULTRAFINE PARTICLE DISPERSION BODY, NEAR-INFRARED-SHIELDING INTERMEDIATE FILM, NEAR-INFRARED-SHIELDING LAMINATED STRUCTURE, AND PRODUCTION METHOD FOR NEAR-INFRARED-SHIELDING ULTRAFINE PARTICLE DISPERSION BODY
  申请人：Sumitomo Metal Mining Co., Ltd.

  公开号：EP3647388A1

  公开（公告）日：2020-05-06

  There are provided a near-infrared shielding ultrafine particle dispersion body, and others, having excellent near-infrared shielding function, low haze value and excellent in design, with suppressed change in color tone during outdoor use and blue haze phenomenon, using near-infrared shielding ultrafine particles transparent in a visible light range, having excellent near-infrared shielding properties, and produced with high productivity, and is provided a near-infrared shielding ultrafine particle dispersion body in which ultra-fine particles having near-infrared shielding properties are dispersed in a solid medium, wherein the ultrafine particles are composite tungsten oxide ultrafine particles (A) represented by a general formula MxWyOz, and have an XRD peak top intensity ratio value of 0.13 or more based on an XRD peak intensity ratio value of 1 on plane (220) of a silicon powder standard sample, and the solid medium contains a resin binder (B) and a weather resistance improver (C), and the weather resistance improver (C) includes at least one selected from a benzotriazole-based UV absorber, a triazine-based UV absorber, and a benzophenone-based UV absorber.

  提供了一种近红外屏蔽超微粒子分散体等，具有优异的近红外屏蔽功能、低雾值和出色的设计，在室外使用时可抑制色调变化和蓝雾现象，使用在可见光范围内透明的近红外屏蔽超微粒子，具有优异的近红外屏蔽性能、提供了一种近红外屏蔽超细粒子分散体，在该分散体中，具有近红外屏蔽性能的超细粒子分散在固体介质中，其中超细粒子是由通式 MxWyOz 表示的复合氧化钨超细粒子 (A)，其 XRD 峰顶强度比值为 0.13 或更高，基于硅粉标准样品平面（220）上的 XRD 峰顶强度比值为 1，固体介质包含树脂粘结剂（B）和耐候性改进剂（C），耐候性改进剂（C）包括至少一种选自苯并三唑类紫外线吸收剂、三嗪类紫外线吸收剂和二苯甲酮类紫外线吸收剂的物质。