5-(2,4,6-tris[bis(trimethylsilyl)methyl]phenyl)-5-mesityl-1,2,3,4,5-tetrathiogermolane | 135139-69-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 5-(2,4,6-tris[bis(trimethylsilyl)methyl]phenyl)-5-mesityl-1,2,3,4,5-tetrathiogermolane
• 英文别名: 5-[2,4,6-tris[bis(trimethylsilyl)methyl]phenyl]-5-mesityl-1,2,3,4,5-tetrathiagermolane；(mesityl)(2,4,6-tris{bis(trimethylsilyl)methyl}phenyl)GeS4；[[3,5-bis[bis(trimethylsilyl)methyl]-2-[5-(2,4,6-trimethylphenyl)tetrathiagermolan-5-yl]phenyl]-trimethylsilylmethyl]-trimethylsilane
• CAS: 135139-69-4
• 化学式: C₃₆H₇₀GeS₄Si₆
• 分子量: 872.319
• InChiKey: KNIZUIJHFWHLKZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  5-(2,4,6-tris[bis(trimethylsilyl)methyl]phenyl)-5-mesityl-1,2,3,4,5-tetrathiogermolane 在 hexamethylphosphorous triamide 、 NaBH₄ 作用下， 以 四氢呋喃 、 苯 为溶剂， 生成 (2,4,6-tris[bis(trimethylsilyl)methyl]phenyl)hydroxy(mesityl)(methylthio)germane
  参考文献：
  名称：

  Synthesis and Structure of Novel Germanium-Containing Cyclic Polysulfides

  摘要：

  Novel germanium-containing cyclic polysulfides 1,2,3,4,5-tetrathiagermolane 5 (Tbt(Ar)GeS4; Tbt = 2,4,6-tris[bis(trimethylsilyl)methyl]phenyl; Ar = mesityl, 2,6-diethylphenyl, 2,4,6-triisopropylphenyl) have been synthesized, and the molecular structure of Tbt(Mes)GeS4 was determined by X-ray crystallographic analysis. Reaction of the tetrathiagermolanes 5 with diphenyldiazomethane gave 1,2,3,5-tetrathia-4-germacyclopentanes 10, 1,2,4,5-tetrathia-3-germacyclohexanes 11, and 1,2,4-trithia-3-germacyclopentanes 12. The structure of 1,2,3,5-tetrathia-4-germacyclohexane 10a was determined by X-ray structural analysis.

  DOI：

  10.1021/om00002a055
• 作为产物：
  描述：

  (2,4,6-tris[bis(trimethylsilyl)methyl]phenyl)bromochloro(mesityl)germane 在 NH₄Cl 、 hexamethylphosphoric triamide 、 t-BuLi 作用下， 以 四氢呋喃 、 水 、 正戊烷 为溶剂， 生成 5-(2,4,6-tris[bis(trimethylsilyl)methyl]phenyl)-5-mesityl-1,2,3,4,5-tetrathiogermolane
  参考文献：
  名称：

  Synthesis and Structure of Novel Germanium-Containing Cyclic Polysulfides

  摘要：

  Novel germanium-containing cyclic polysulfides 1,2,3,4,5-tetrathiagermolane 5 (Tbt(Ar)GeS4; Tbt = 2,4,6-tris[bis(trimethylsilyl)methyl]phenyl; Ar = mesityl, 2,6-diethylphenyl, 2,4,6-triisopropylphenyl) have been synthesized, and the molecular structure of Tbt(Mes)GeS4 was determined by X-ray crystallographic analysis. Reaction of the tetrathiagermolanes 5 with diphenyldiazomethane gave 1,2,3,5-tetrathia-4-germacyclopentanes 10, 1,2,4,5-tetrathia-3-germacyclohexanes 11, and 1,2,4-trithia-3-germacyclopentanes 12. The structure of 1,2,3,5-tetrathia-4-germacyclohexane 10a was determined by X-ray structural analysis.

  DOI：

  10.1021/om00002a055

文献信息

• The First Kinetically Stabilized Germanethiones and Germaneselones:  Syntheses, Structures, and Reactivities
  作者：Tsuyoshi Matsumoto、Norihiro Tokitoh、Renji Okazaki

  DOI：10.1021/ja991147x

  日期：1999.9.1

  of the novel 1,2,3,4,5-tetrachalcogenagermolane Tbt(Tip)GeX4 (Tbt = 2,4,6-tris[bis(trimethylsilyl)methyl]phenyl, Tip = 2,4,6-triisopropylphenyl, X = S or Se) with 3 molar equiv of triphenylphosphine gave diaryl-substituted germanethione Tbt(Tip)GeS 1a and germaneselone Tbt(Tip)GeSe 2a as orange−yellow crystals and red crystals, respectively, which were unstable in air but thermally quite stable. Chalcogenation

  合成了第一个动力学稳定的锗硫酮（锗-硫双键物种）和锗烷酮（锗-硒双键物种）。新型 1,2,3,4,5-四硫属元素格尔莫烷 Tbt(Tip)GeX4（Tbt = 2,4,6-三[双（三甲基甲硅烷基）甲基]苯基，Tip = 2,4,6-三异丙基苯基，X）的脱硫= S 或 Se) 与 3 摩尔当量的三苯基膦得到二芳基取代的锗硫酮 Tbt(Tip)GeS 1a 和锗烷硫酮 Tbt(Tip)GeSe 2a 分别为橙黄色晶体和红色晶体，它们在空气中不稳定但热稳定. 锗烯 Tbt(Dis)Ge 的硫氢化作用：导致分离出相应的锗烷硫酮 Tbt(Dis)GeS 1b 和锗烷硫酮 Tbt(Dis)GeSe 2b（Dis = 双（三甲基甲硅烷基）甲基）。锗烷硫酮 1a 和锗烷硫酮 2a 的分子结构，
• Okazaki, Renji; Tokitoh, Norihiro; Ishii, Akihiko, Phosphorus, Sulfur and Silicon and the Related Elements, 1992, vol. 67, # 1-4, p. 49 - 66
  作者：Okazaki, Renji、Tokitoh, Norihiro、Ishii, Akihiko、Ishii, Naoko、Matsuhashi, Yasusuke、et al.

  DOI：——

  日期：——
• Tokitoh, Norihiro; Takahashi, Masaki; Matsumoto, Tsuyoshi, Phosphorus, Sulfur and Silicon and the Related Elements
  作者：Tokitoh, Norihiro、Takahashi, Masaki、Matsumoto, Tsuyoshi、Suzuki, Hiroyiki、Matsuhashi, Yasusuke、et al.

  DOI：——

  日期：——
• Okazaki, Renji; Matsuhashi, Yasusuke; Matsumoto, Tsuyoshi, Phosphorus, Sulfur and Silicon and the Related Elements, 1993, vol. 74, # 1-4, p. 397 - 398
  作者：Okazaki, Renji、Matsuhashi, Yasusuke、Matsumoto, Tsuyoshi、Saito, Masaichi、Manmaru, Kyoko、Tokitoh, Norihiro

  DOI：——

  日期：——
• Tokitoh, Norihiro; Suzuki, Hiroyuki; Matsumoto, Tsuyoshi, Journal of the American Chemical Society, 1991, vol. 113, p. 7047 - 7049
  作者：Tokitoh, Norihiro、Suzuki, Hiroyuki、Matsumoto, Tsuyoshi、Matsuhashi, Yasusuke、Okazaki, Renji

  DOI：——

  日期：——