[Zn(N-(2-pyridylmethyl)acetamide)2(OTf)2] | 949085-24-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯
• 英文名称: [Zn(N-(2-pyridylmethyl)acetamide)2(OTf)2]
• CAS: 949085-24-9
• 化学式: C₁₈H₂₀F₆N₄O₈S₂Zn
• 分子量: 663.891
• InChiKey: YATYBVUPBZQMMX-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  2-乙酰氨基甲基吡啶 、 zinc trifluoromethanesulfonate 以 乙腈 为溶剂， 以92%的产率得到[Zn(N-(2-pyridylmethyl)acetamide)2(OTf)2]
  参考文献：
  名称：

  Substituted pyridylmethylamide ligands and their zinc complexes

  摘要：

  Mononuclear zinc complexes of a family of pyridylmethylamide ligands abbreviated as HL, HLPh, HLMe3, HLPh3, and MeLsMe [HL = N-(2-pyridylmethyl)acetamide; HLPh = 2-phenyl-N-(2-pyridylmethyl)acetamide; HLMe3 = 2,'2-dimethyl-N-(2-pyridylmethyl)propionamide; HLPh3 = 2,2,2-triphenyl-N-(2-pyridylmethyl)acetamide; MeLSMe = N-methyl-2-methylsulfanyl-N-pyridin-2-ylmethyl-acetamide] were synthesized and characterized spectroscopically and by single crystal X-ray structural analysis. The reaction of zinc(II) salts with the HL ligands yielded complexes [Zn(HL)(2)(OTf)(2)] (1), [Zn(HL)(2)(H2O)](ClO4)(2) (2), [Zn(HLPh3)(2)(H2O)](CLO4)(2) (3), [Zn(HLPh)Cl-2] (4), [Zn(HLMe3) Cl-2] (5), and [Zn(MeLSMe)Cl-2] (6). The complexes are either four-, five- or six-coordinate, encompassing a variety of geometries including tetrahedral, square-pyramidal, trigonal-bipyramidal, and octahedral. (c) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2007.05.003