2-(2,5-di(thiophen-2-yl)thiophen-3-yl)acetic acid | 163463-81-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 双噻吩和低聚噻吩
• 英文名称: 2-(2,5-di(thiophen-2-yl)thiophen-3-yl)acetic acid
• 英文别名: 2,2':5',2''-terthiophene-3'-acetic acid；2-(2,5-dithiophen-2-ylthiophen-3-yl)acetic acid
• CAS: 163463-81-8
• 化学式: C₁₄H₁₀O₂S₃
• 分子量: 306.43
• InChiKey: CMHBJBNCKKYFOU-UHFFFAOYSA-N

物化性质

• 沸点：
  477.2±45.0 °C(Predicted)
• 密度：
  1.419±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.8
• 重原子数：
  19
• 可旋转键数：
  4
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.07
• 拓扑面积：
  122
• 氢给体数：
  1
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  1,3,3-trimethyl-9'-hydroxyspiro[indoline-2,3'-[3H]naphtho[2,1-b](1,4)oxazine] 、 2-(2,5-di(thiophen-2-yl)thiophen-3-yl)acetic acid 在 2,3-二脱氧胞啶 作用下， 以 二氯甲烷 为溶剂， 生成 (1',3',3'-Trimethylspiro[benzo[f][1,4]benzoxazine-3,2'-indole]-9-yl) 2-(2,5-dithiophen-2-ylthiophen-3-yl)acetate
  参考文献：
  名称：

  Synthesis and electropolymerization of terthienyl carrying a photochromic group

  摘要：

  A photochromic spironaphthoxazine group is covalently bonded to the 3'-position of terthienyl and the 3-position of thiophene; electropolymerization into spironaphthoxazine-functionalized polythiophene only occurs with the use of the spironaphthoxazine-terthiophene compound as the monomer.

  DOI：

  10.1039/c39950000471
• 作为产物：
  描述：

  3-噻吩乙酸 在 甲醇 、 bis-triphenylphosphine-palladium(II) chloride 、 N-溴代丁二酰亚胺(NBS) 、 氯化亚砜 、 potassium carbonate 、 potassium hydroxide 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 生成 2-(2,5-di(thiophen-2-yl)thiophen-3-yl)acetic acid
  参考文献：
  名称：

  电聚合得到的TEMPO修饰的聚对噻吩电极的制备及电化学性能

  摘要：

  具有侧链TEMPO的新型对噻吩单体，4-（2,5-二（噻吩-2-基）噻吩-3-基）乙酰氧基-2,2,6,6-四甲基哌啶-1-基氧基（ TT-TEMPO）已成功合成。通过在三氟化硼二乙基醚化物溶液中的Pt电极上进行电化学聚合，制备了其相应的聚合物PTT-TEMPO。PTT-TEMPO膜显示出均匀的网络结构。与裸露的Pt电极相比，PTT-TEMPO电极在类似条件下，在2,6-二甲基吡啶存在下，对苯甲醇的氧化具有较高的电催化性能。根据原位FTIR分析，将苄醇选择性氧化为苯甲醛。

  DOI：

  10.1016/j.elecom.2019.106623

文献信息

• Reversible sensing of aqueous mercury using a rhodamine-appended polyterthiophene network on indium tin oxide substrates
  作者：Chatthai Kaewtong、Noi Niamsa、Buncha Pulpoka、Thawatchai Tuntulani

  DOI：10.1039/c4ra11353e

  日期：——

  demonstrates ion selective potentiometric, chromic and fluorescent responses. The rhodamine-appended terthiophene monomer (RhoT) was electropolymerized and deposited on an ITO electrode. Ion selective potentiometric studies have shown that the potentials of the conducting polymer films decreased upon adding Hg2+ because interactions of Hg2+ with the rhodamine-appended conducting polymer film may increase

  在本文中，我们报告了若丹明附加的聚对噻吩网络薄膜的合成，光学和电化学性质，证明了离子选择电位，色度和荧光响应。将附有若丹明的三联噻吩单体（RhoT）电聚合并沉积在ITO电极上。离子选择性电位研究表明，添加Hg 2+后，导电聚合物薄膜的电势降低，因为Hg 2+与若丹明附加的导电聚合物薄膜的相互作用可能会增加通过若丹明结合的Hg 2在共轭聚合物上的电荷载流子传输性质。+通过干扰离子与离子的相互作用来减少离子的掺杂状态，并通过π-π的相互作用干扰π扩展的共轭聚合物。另外，超薄膜传感器对Hg 2+的检测下限（0.10μM）小于从RhoT获得的下限（1.34μM），响应时间小于30秒。通过在Hg 2+和EDTA水溶液中重复浸泡和漂洗循环来评估可重复使用性。这种方法可以为环境和生物应用中的Hg 2+离子检测提供一种易于测量且固有敏感的方法。
• Method of crosslinking intrinsically conductive polymers or intrinsically conductive polymer precursors and the articles obtained therefrom
  申请人：——

  公开号：US20040242792A1

  公开（公告）日：2004-12-02

  A method of manufacturing an intrinsically conductive polymer crosslinking at least a portion of an intrinsically conductive polymer precursor in the solid state, the swollen state, or combinations comprising at least one of the foregoing states, wherein the swollen state is characterized as being one wherein the intrinsically conductive polymer precursor increases in volume upon exposure to a solvent without completely dissolving in the solvent. In another embodiment, a method of manufacturing a pattern comprises casting a film of an intrinsically conductive polymer precursor on a substrate; and crosslinking at least a portion of the film by oxidation, wherein the crosslinking occurs in the solid state, the swollen state or combinations comprising at least one of the foregoing states.

  一种制造固态、膨胀态或包括上述状态中至少一种状态的本质导电聚合物交联的方法，其中膨胀态被表征为在暴露于溶剂时，本质导电聚合物前体体积增大而不完全溶解于溶剂中。在另一实施例中，一种制造图案的方法包括在基板上铸造本质导电聚合物前体的薄膜；通过氧化交联至少部分薄膜，其中交联发生在固态、膨胀态或包括上述状态中至少一种状态中。
• SENSORS AND SEPARATION BASED ON MOLECULAR RECOGNITION VIA ELECTROPOLYMERIZATION AND COLLOIDAL LAYER TEMPLATES
  申请人：Advincula Rigoberto

  公开号：US20120263922A1

  公开（公告）日：2012-10-18

  Novel coatings are disclosed prepared from electropolymerization of electropolymerizable monomers-analyte complexes onto a conducting layer or non-conducting of a substrate, where the analyte is removed by electrochemically mediated washing permitting linear molecular sensing of the analyte over a wide concentration range. The coating may also include templating particles deposited on the electrode substrate prior to electropolymerization, where the particles can be removed to form a submicron structured coating. Methods for making and using the coatings are also disclosed.

  本发明揭示了一种新型涂层，是由可电聚合单体-分析物复合物通过电聚合方法沉积在导电层或非导电基底上制备而成的。其中，通过电化学介导的清洗方法去除了分析物，使得分析物在广泛浓度范围内能够线性地分子感应。涂层还可以包括在电极基底上沉积模板颗粒进行电聚合之前，可以去除颗粒以形成亚微米结构涂层。本发明还揭示了制备和使用这种涂层的方法。
• NEW TYPES OF ELECTRODEPOSITED POLYMER COATINGS WITH REVERSIBLE WETTABILITY AND ELECTRO-OPTICAL PROPERTIES
  申请人：UNIVERSITY OF HOUSTON SYSTEM

  公开号：US20160237305A1

  公开（公告）日：2016-08-18

  Novel coatings are disclosed prepared by electropolymerization of non-fluorinated conducting pre-grafted hydrophobic electropolymerizable monomers onto a conducting layer of a substrate, where the electropolymerized coating exhibit both unique reversible wettability and electro-optical properties. The coating may also include one or more layers of polymer particles upon which the non-fluorinated conducting pre-grafted hydrophobic electropolymerizable monomers are polymerized imparting a submicron structure to the coating. Methods for making and using the coatings are also disclosed.

  本发明揭示了一种新型涂层，通过将非氟化导电预接枝疏水电聚合单体电聚合到基底的导电层上制备而成，其中电聚合涂层具有独特的可逆润湿性和电光性能。该涂层还可以包括一层或多层聚合物颗粒，其中非氟化导电预接枝疏水电聚合单体被聚合，从而赋予涂层亚微米结构。还揭示了制备和使用该涂层的方法。
• Redox nanoreactor dendrimer boxes: in situ hybrid gold nanoparticles via terthiophene and carbazole peripheral dendrimer oxidation
  作者：Chatthai Kaewtong、Guoqian Jiang、Ramakrishna Ponnapati、Buncha Pulpoka、Rigoberto Advincula

  DOI：10.1039/c0sm00796j

  日期：——

  π-Conjugated dendrimer-protected gold nanoparticles in stable colloidal form have been successfully prepared via simultaneous reduction of AuCl3 with oxidative polymerization of terthiophene (PT) and carbazole (PC) peripheral functionalized polyamidoamine (PAMAM) dendrimers. The hybrid dendrimer–metal materials were characterized by UV-vis, fluorescence, and FT-IR spectroscopy. XPS and AFM analyses were also employed. The differences in gold nanoparticle (AuNP) formation between the two PAMAM derivatives were discussed. In case of PT dendrimer, AuNPs can be stabilized in situ to form PAMAM–PPT–AuNP hybrid materials. For the PC dendrimer, the redox reaction afforded carbazole polymerization without necessarily forming AuNPs.

  通过同时还原AuCl3与氧化聚合三噻吩（PT）和咔唑（PC）外围官能化的聚酰胺胺（PAMAM）树枝状聚合物，已成功制备出稳定胶体形式的π-共轭树枝状聚合物保护金纳米粒子。通过紫外-可见光、荧光和傅立叶变换红外光谱对树枝状聚合物-金属杂化材料进行了表征。还采用了XPS和AFM分析。讨论了两种PAMAM衍生物在金纳米粒子（AuNP）形成方面的差异。对于PT树枝状聚合物，AuNP可以在原位稳定形成PAMAM-PPT-AuNP杂化材料。对于PC树枝状聚合物，氧化还原反应提供了咔唑聚合，而不一定形成AuNP。