[Pt(OAc)(O2CCH2SMe)(MeSCH2C(O)OEt)] | 844466-99-5

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: [Pt(OAc)(O2CCH2SMe)(MeSCH2C(O)OEt)]
• CAS: 844466-99-5
• 化学式: C₂H₃O₂*C₃H₅O₂S*C₅H₁₀O₂S*Pt
• 分子量: 493.461
• InChiKey: DVSNNVVFBSNWIY-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  -1.23
• 重原子数：
  19.0
• 可旋转键数：
  5.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.7
• 拓扑面积：
  106.56
• 氢给体数：
  0.0
• 氢受体数：
  8.0

反应信息

• 作为反应物：
  描述：

  [Pt(OAc)(O2CCH2SMe)(MeSCH2C(O)OEt)] 以 二氯甲烷 为溶剂， 生成
  参考文献：
  名称：

  Chloro and acetato complexes of platinum(II) with functionalized thioethers

  摘要：

  The chloro complexes [PtCl2(RSR')(2)] (1-10) (RSR' = MeSCH2C(O)OMe, 1; MeSCH2C(O)OEt, 2; MeSCH2C(O)Omenthyl(-), 3: MeSCH2CH2C(O)OMe, 4; S(CH2)(3)CHC(O)OEt, 5; EtSCH2C(O)Me; 6; MeSCH C(O)Me, 7; MeSPh, 8; MeS-o-C6H4Me, 9; and MeS-o-C6H4Et, 10) are obtained in high yield (63-90%) by reaction of [PtCl2(PhCN)(2)] with the proper thioether in 1/2 molar ratio. in anhydrous chloroform. at reflux under argon for ca. 10 h. The X-ray crystal structure of [PtCl2(MeS-o-C6H4Me)(2)] (9) shows an almost regular trans square planar geometry (triclinic, space group P (1) over bar, a 6.806(1), b 7.789(2), c 10.085(3) Angstrom, alpha 101.80(2)degrees, beta 69.55(2)degrees, gamma 115.27(2)degrees, R(F-o) 0.023, R-w(F-o(2)) 0.065). The dichloro complexes react with silver acetate in a complex manner, which depends on the nature of the thioether, and only with RSR' = MeSPh the simple diacetato complex [Pt(OAc)(2)(RSR')(2)] is obtained as the major product. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2004.10.014
• 作为产物：
  描述：

  trans-[PtCl2(MeSCH2C(O)OEt)2] 、 silver(I) acetate 以 二氯甲烷 为溶剂， 以32%的产率得到[Pt(OAc)(O2CCH2SMe)(MeSCH2C(O)OEt)]
  参考文献：
  名称：

  Chloro and acetato complexes of platinum(II) with functionalized thioethers

  摘要：

  The chloro complexes [PtCl2(RSR')(2)] (1-10) (RSR' = MeSCH2C(O)OMe, 1; MeSCH2C(O)OEt, 2; MeSCH2C(O)Omenthyl(-), 3: MeSCH2CH2C(O)OMe, 4; S(CH2)(3)CHC(O)OEt, 5; EtSCH2C(O)Me; 6; MeSCH C(O)Me, 7; MeSPh, 8; MeS-o-C6H4Me, 9; and MeS-o-C6H4Et, 10) are obtained in high yield (63-90%) by reaction of [PtCl2(PhCN)(2)] with the proper thioether in 1/2 molar ratio. in anhydrous chloroform. at reflux under argon for ca. 10 h. The X-ray crystal structure of [PtCl2(MeS-o-C6H4Me)(2)] (9) shows an almost regular trans square planar geometry (triclinic, space group P (1) over bar, a 6.806(1), b 7.789(2), c 10.085(3) Angstrom, alpha 101.80(2)degrees, beta 69.55(2)degrees, gamma 115.27(2)degrees, R(F-o) 0.023, R-w(F-o(2)) 0.065). The dichloro complexes react with silver acetate in a complex manner, which depends on the nature of the thioether, and only with RSR' = MeSPh the simple diacetato complex [Pt(OAc)(2)(RSR')(2)] is obtained as the major product. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2004.10.014