2-(1-Hydroxy-1-methyl-ethyl)-butanediperoxoic acid di-tert-butyl ester | 35489-51-1

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: 2-(1-Hydroxy-1-methyl-ethyl)-butanediperoxoic acid di-tert-butyl ester
• 英文别名: Ditert-butyl 2-(2-hydroxypropan-2-yl)butanediperoxoate
• CAS: 35489-51-1
• 化学式: C₁₅H₂₈O₇
• 分子量: 320.383
• InChiKey: LBUOHEDRSQXWEI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.9
• 重原子数：
  22
• 可旋转键数：
  10
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.87
• 拓扑面积：
  91.3
• 氢给体数：
  1
• 氢受体数：
  7

文献信息

• Process for preparing peroxides using mixed anhydrides
  申请人：——

  公开号：US20040049070A1

  公开（公告）日：2004-03-11

  The invention relates to a process for the preparation of a peracid, perester or diacylperoxide and is characterized in that a mixed anhydride of formula R 1 [C(O)OC(O)OR 2 ] n or [R 3 C(O)OC(O)O] p R 4 is contacted with a hydroperoxide of formula R 5 [OOH] m in the presence of a base, wherein R 1 represents a mono-, di-, tri- or tetravalent C 1 -C 19 hydrocarbon group, optionally containing one or more hetero atoms, n is 1-4, R 2 represents a C 1 -C 20 hydrocarbon group, optionally containing one or more hetero atoms, R 3 represents a C 1 -C 19 hydrocarbon group, optionally containing one or more hetero atoms, R 4 represents a di-, tri- or tetravalent C 1 -C 20 hydrocarbon group, optionally containing one or more hetero atoms, p is 2-4, R 5 represents hydrogen or a mono- or divalent C 3 -C 18 tertiary alkyl or C 2 -C 20 acyl group, in which the tertiary alkyl or acyl group may optionally contain one or more hetero atoms, m is 1 or 2, and if R 5 represents hydrogen, m is 1, provided that if the hydroperoxide is an &agr;,&agr;′-dihydroperoxyperoxide, the reaction is not carried out in an inert two-phase solvent system comprising a polar solvent and an apolar solvent. The invention also relates to a hydroxyperacid, hydroxyperester, and hydroxydiacylperoxide obtainable by said process and the use of said hydroxyperoxides.

  本发明涉及一种制备过酸、过酯或双酰过氧化物的方法，其特征在于将式R1[C(O)OC(O)OR2]n或[R3C(O)OC(O)O]pR4的混合酸酐与式R5[OOH]的过氧化氢在碱的存在下接触，其中R1表示一个单、双、三或四价的C1-C19烃基，可选地含有一个或多个杂原子，n为1-4，R2表示一个C1-C20烃基，可选地含有一个或多个杂原子，R3表示一个C1-C19烃基，可选地含有一个或多个杂原子，R4表示一个双、三或四价的C1-C20烃基，可选地含有一个或多个杂原子，p为2-4，R5表示氢或一个单价或双价的C3-C18三级烷基或C2-C20酰基，其中该三级烷基或酰基可选地含有一个或多个杂原子，m为1或2，如果R5表示氢，则m为1，但如果过氧化氢是α，α'-二过氧基过氧化物，则不在惰性双相溶剂系统中进行反应，该系统包括一个极性溶剂和一个非极性溶剂。本发明还涉及通过该方法获得的羟基过酸、羟基过酯和羟基双酰过氧化物以及所述羟基过氧化物的用途。
• PROCESS FOR PREPARING PEROXIDES USING MIXED ANHYDRIDES
  申请人：Akzo Nobel N.V.

  公开号：EP1220837A1

  公开（公告）日：2002-07-10
• [EN] PROCESS FOR PREPARING PEROXIDES USING MIXED ANHYDRIDES<br/>[FR] PROCEDE DE PREPARATION DE PEROXYDES A L'AIDE D'ANHYDRIDES MELANGES
  申请人：AKZO NOBEL NV

  公开号：WO2001027078A1

  公开（公告）日：2001-04-19

  The invention relates to a process for the preparation of a peracid, perester or diacylperoxide and is characterized in that a mixed anhydride of formula: R1[C(O)OC(O)OR2]n or [R3C(O)OC(O)O]¿pR?4 is contacted with a hydroperoxide of formula: R5[OOH]m in the presence of a base, wherein R1 represents a mono-, di-, tri- or tetravalent C¿1?-C19 hydrocarbon group, optionally containing one or more hetero atoms, n is 1-4, R?2¿ represents a C¿1?-C20 hydrocarbon group, optionally containing one or more hetero atoms, R?3¿ represents a C¿1?-C19 hydrocarbon group, optionally containing one or more hetero atoms, R?4¿ represents a di-, tri- or tetravalent C¿1?-C20 hydrocarbon group, optionally containing one or more hetero atoms, p is 2-4, R?5¿ represents hydrogen or a mono- or divalent C¿3?-C18 tertiary alkyl or C2-C20 acyl group, in which the tertiary alkyl or acyl group may optionally contain one or more hetero atoms, m is 1 or 2, and if R?5¿ represents hydrogen, m is 1, provided that if the hydroperoxide is an α,α-dihydroperoxyperoxide, the reaction is not carried out in an inert two-phase solvent system comprising a polar solvent and an polar solvent. The invention also relates to a hydroxyperacid, hydroxyperester, and hydroxydiacylperoxide obtainable by said process and the use of said hydroxyperoxides.