MoCl(CO)2(NCMe)(η(3)-C3H4(Ch2Cl-2))(pyridine-3-carboxylic acid, sodium salt) | 201469-81-0

• 英文名称: MoCl(CO)2(NCMe)(η(3)-C3H4(Ch2Cl-2))(pyridine-3-carboxylic acid, sodium salt)
• CAS: 201469-81-0
• 化学式: C₁₄H₁₃Cl₂MoN₂O₄*Na
• 分子量: 463.104
• InChiKey: XDLYMZOJTLGCIY-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  MoCl(CO)2(NCMe)2(η(3)-C3H4(CH2Cl-2)) 、 sodium nicotinate 以 甲醇 、 丙酮 为溶剂， 以73%的产率得到MoCl(CO)2(NCMe)(η(3)-C3H4(Ch2Cl-2))(pyridine-3-carboxylic acid, sodium salt)
  参考文献：
  名称：

  Synthesis and characterisation of some new water soluble π-allyl dicarbonyl complexes of molybdenum(II)

  摘要：

  Equimolar quantities of [MoX(CO)(2)(NCMe)(2)(theta(3)-C(3)H(4)R)] and L react in methanol/acetone to give high yields of the acetonitrile displaced complexes [MoX(CO)(2)(NCMe)L(eta(3)-C(3)H(4)R)] {X = Br, L = 3-NaO(2)CC(5)H(4)N, 4-NaO(2)CC(5)H(4)N, 3-NaO(3)SC(5)H(4)N, R = H; X = Cl, L = 3-NaO(2)CC(5)H(4)N, R = H, CH(2)Cl-2; X = Cl, L = 4-NaO(2)CC(5)H(4)N, R = H, CH(2)Cl-2; X = Cl, L = 3,4-(NaO(2)C)(2)C(5)H(3)N, R = CH(3)-2}. Reaction of [MoX(CO)(2)(NCMe)(2)(eta(3)-C(3)H(4)R)] with two equivalents of L in methanol/acetone gave the his (substituted) pyridine complexes [MoX(CO)(2)L(2)(eta(3)-C(5)H(4)R)] {X = Br, L = 3-NaO(2)CC(5)H(4)N, 4-NaO(2)CC(5)H(4)N, 3,5-(NaO(2)C)(2)C(5)H(3)N, 3-NaO(3)SC(5)H(4)N, R = H; X = Cl, L = 3-NaO(2)CC(5)H(4)N, R = H, CH(3)-2; X = Cl, L = 4-NaO(2)CC(5)H(4)N, R = CH(3)-2; X = Cl, L = 3, 4-(NaO(2)C)(2)C(5)H(3)N, R = H; X = Cl, L = 3-NaO(3)SC(5)H(4)N, R = H, CH(3)-2} in high yield. The water solubility of these complexes has been investigated, and the NaO(3)SC(5)H(4)N ligand complexes were found to be completely water soluble. (C) 1997 Elsevier Science S.A.

  DOI：

  10.1016/s0022-328x(97)00222-2