dibromo(1,4,7,10-tetraazacyclotridecane-κ(4)N(1),N(4),N(7),N(10))nickel(III) bromide | 138497-34-4

• 分子结构分类: 有机化合物 - 有机杂环化合物
• 英文名称: dibromo(1,4,7,10-tetraazacyclotridecane-κ(4)N(1),N(4),N(7),N(10))nickel(III) bromide
• CAS: 138497-34-4
• 化学式: Br*C₉H₂₂Br₂N₄Ni
• 分子量: 484.702
• InChiKey: ZNPVTBQZXXIUNS-UHFFFAOYSA-K

反应信息

• 作为产物：
  描述：

  {Ni(1,4,7,10-tetraazacyclotridecane)Br2}ClO4 以 乙腈 为溶剂， 生成 dibromo(1,4,7,10-tetraazacyclotridecane-κ(4)N(1),N(4),N(7),N(10))nickel(III) bromide
  参考文献：
  名称：

  Co-ordination of 1,4,7,10-tetraazacyclotridecane ([13]aneN4) to nickel(III). Crystal structure of [Ni([13]aneN4)Br2]Br

  摘要：

  The crystal structure of [Ni([13]aneN4)Br2]Br ([13]aneN4 = 1,4,7,10-tetraazacyclotridecane) has been determined by single-crystal X-ray diffraction: tetragonal, space group P4(2) with a = 7.8502(9), c = 12.464(2) angstrom and Z = 2. The Ni atom on the crystallographic two-fold axis is surrounded octahedrally by a square-planar array of four N atoms from the macrocycle with two bromide ions occupying the axial positions. The carbon atoms of the macrocycle are too disordered to be depicted because of the unexpected crystallographic symmetry. The tetragonal co-ordination geometry found in this complex is consistent with the proposed on the basis of the ESR spectrum in dimethyl sulphoxide. The correlation between the in-plane Ni-N and axial Ni-Br distances is discussed in terms of the size of the aperture in the cyclic ligand.

  DOI：

  10.1039/dt9910002921