(E)-Octadecyl-4-<2-(4-diethylaminophenyl)ethenyl>pyridinium iodide | 155373-29-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (E)-Octadecyl-4-<2-(4-diethylaminophenyl)ethenyl>pyridinium iodide
• 英文别名: (E)-N-octadecyl-4-[2-(4-diethylaminophenyl)ethenyl]pyridinuim iodide；N,N-diethyl-4-[2-(1-octadecylpyridin-1-ium-4-yl)ethenyl]aniline;iodide
• CAS: 155373-29-8；181777-44-6
• 化学式: C₃₅H₅₇N₂*I
• 分子量: 632.755
• InChiKey: GADOUMJYKWCIOP-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  7.26
• 重原子数：
  38
• 可旋转键数：
  22
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.63
• 拓扑面积：
  7.1
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  bis(tetrabutylammonium) bis(2-thione-1,3-dithiol-4,5-dimercapto) zinc 、 (E)-Octadecyl-4-<2-(4-diethylaminophenyl)ethenyl>pyridinium iodide 以 乙醇 、 丙酮 为溶剂， 生成 bis(E)-N-octadecyl-4-[2-(4-diethylaminophenyl)ethenyl]pyridinuim bis(2-thione-1,3-dithiol-4,5-dimerkapto) zinc
  参考文献：
  名称：

  Langmuir–Blodgett film and second harmonic generation of a new type of amphiphilic non-linear optical bis-chromophore complex dye

  摘要：

  A bivalent zinc complex anion: bis(2-thione-1,3-dithiol-4,5-dimercapto)zinc, has been chosen to balance several non-linear optical (NLO) dye cations in the design and synthesis of a series of novel bis-chromophore complex dyes. The Langmuir film-forming properties of these new NLO complex dyes at the air/water interface, the stability and second-order non-linear optical properties of the monolayer and Langmuir-Blodgett multilayer films were investigated. Results show that both the film-forming properties and NLO coefficiencies were improved greatly when the zinc complex anion was incorporated into four types of NLO-active organic dyes.

  DOI：

  10.1039/ft9969202585
• 作为产物：
  描述：

  4-甲基吡啶 在 哌啶 作用下， 以 乙醇 为溶剂， 反应 76.0h， 生成 (E)-Octadecyl-4-<2-(4-diethylaminophenyl)ethenyl>pyridinium iodide
  参考文献：
  名称：

  Langmuir–Blodgett film and second harmonic generation of a new type of amphiphilic non-linear optical bis-chromophore complex dye

  摘要：

  A bivalent zinc complex anion: bis(2-thione-1,3-dithiol-4,5-dimercapto)zinc, has been chosen to balance several non-linear optical (NLO) dye cations in the design and synthesis of a series of novel bis-chromophore complex dyes. The Langmuir film-forming properties of these new NLO complex dyes at the air/water interface, the stability and second-order non-linear optical properties of the monolayer and Langmuir-Blodgett multilayer films were investigated. Results show that both the film-forming properties and NLO coefficiencies were improved greatly when the zinc complex anion was incorporated into four types of NLO-active organic dyes.

  DOI：

  10.1039/ft9969202585

文献信息

• OPTICALLY NON-LINEAR MATERIALS
  申请人：BRITISH TECHNOLOGY GROUP LIMITED

  公开号：EP0642678A1

  公开（公告）日：1995-03-15
• [EN] OPTICALLY NON-LINEAR MATERIALS<br/>[FR] MATERIAUX OPTIQUEMENT NON LINEAIRES
  申请人：BRITISH TECHNOLOGY GROUP LTD.

  公开号：WO1993024859A1

  公开（公告）日：1993-12-09

  (EN) The invention relates to novel optically non-linear materials comprising a film forming hemicyanine dye having an amphiphilic anion.(FR) Cette invention concerne de nouveaux matériaux optiquement non linéaires constitués d'un colorant filmogène à l'hémicyanine comprenant un anion amphiphile.