[(Zn[pz(t-butylphenyl)6phen])Ru(Cp)PPh3]Cl | 356788-39-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [(Zn[pz(t-butylphenyl)6phen])Ru(Cp)PPh3]Cl
• CAS: 356788-39-1
• 化学式: C₅H₅*C₁₈H₁₅P*C₈₈H₈₄N₁₂Zn*Cl*Ru
• 分子量: 1839.01
• InChiKey: OIZVBCNFYUIOLY-UHFFFAOYSA-M

反应信息

• 作为产物：
  描述：

  二(三苯基膦)环戊二烯基氯化钌(II) 、 Zn[pz(t-butylphenyl)6phen]*3H2O 以 N,N-二甲基甲酰胺 为溶剂， 以55%的产率得到[(Zn[pz(t-butylphenyl)6phen])Ru(Cp)PPh3]Cl
  参考文献：
  名称：

  Phenanthroline-appended porphyrazines: synthesis and conversion into solitaire Ru(II) complexes

  摘要：

  Unsymmetrical porphyrazines (tetraazaporphyrins) bearing a single bidentate phenanthroline chelating group M[pz(t-butylphenyl)(6)phen] have been prepared by the base-catalyzed cross condensation of 3,4-bis(4-tert-butylphenyl)pyrroline-2,5-diimine (in excess) with 6,7-dicyanodipyridoquinoxaline. Treatment of these centrally metalated (M = Mg, Zn) ligands with various Ru(II) salts has yielded several bimetallic complexes including the first coordinatively linked porphyrazine trimer. The optical properties of these complexes are shown to be a function of the additional ligands surrounding the asymmetric ruthenium center. (C) 2001 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(01)00325-5