trans-diazidocyclammanganese(III) triflate | 887340-58-1

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机磺酸及其衍生物
• 英文名称: trans-diazidocyclammanganese(III) triflate
• CAS: 887340-58-1
• 化学式: CF₃O₃S*C₁₀H₂₄MnN₁₀
• 分子量: 488.376
• InChiKey: MQPBFLDHYQUBCC-UHFFFAOYSA-M

反应信息

• 作为产物：
  描述：

  trans-[Mn(1,4,8,11-tetraazacyclotetradecane)(H2O)2](CF3SO3)3*H2O 、 sodium azide 以 水 为溶剂， 以63%的产率得到trans-diazidocyclammanganese(III) triflate
  参考文献：
  名称：

  Manganese (III) cyclam complexes with aqua, iodo, nitrito, perchlorato and acetic acid/acetato axial ligands

  摘要：

  The syntheses, structures and magnetic properties of five new manganese (III) cyclam complexes, trans-[Mn(cyclam)(OH2)(2)]-(CF3SO3)(3)center dot-H2O, trans-[Mn(cyclam)I-2]I, trans-[Mn(cyclam)(ONO)(2)]ClO4, trans-[Mn(cyclam)(OClO3)(2)]ClO4 and trans-[Mn(cyclam) (CH3COO)(CH3COOH)](ClO4)(2), are reported. Cyclam is the tetradentate amine ligand 1,4,8,11-tetraazacyclotetradecane. The complexes all exhibit pronounced tetragonal elongation of the coordination octahedron with the four cyclam nitrogens occupying the four equatorial positions. The magnetic properties are consistent with the formulation of the complexes as high-spin d(4) systems. trans-[Mn(cyclam)(OH2)(2)](CF3SO3)(3)center dot H2O is shown to be a convenient starting material for the syntheses of trans cyclam complexes. [Mn(cyclam)(CH3COO)(CH3COOH)](ClO4)(2) exhibits extremely short intermolecular hydrogen bonds resulting in a pseudo-chain structure. The tilt of the axial ligands with respect to the equatorial plane containing the manganese and the cyclam nitrogen atoms is discussed. (c) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2004.10.005