copper(II) 2,3,7,8,12,13,17,18-octakis(octylthio)-5,10,15,20-tetraazaporphyrine | 133347-53-2

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫醚类
• 英文名称: copper(II) 2,3,7,8,12,13,17,18-octakis(octylthio)-5,10,15,20-tetraazaporphyrine
• 英文别名: Cu-octakis(octylthio)tetraazaporphyrin；copper;4,5,9,10,14,15,19,20-octakis(octylsulfanyl)-2,7,12,17,21,23-hexaza-22,24-diazanidapentacyclo[16.2.1.13,6.18,11.113,16]tetracosa-1,3,5,7,9,11(23),12,14,16,18(21),19-undecaene
• CAS: 133347-53-2
• 化学式: C₈₀H₁₃₆CuN₈S₈
• 分子量: 1530.09
• InChiKey: YMQIRDMWSNHARQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  2,3,7,8,12,13,17,18-octakis(octylsulfanyl)-5,10,15,20-21H,23H-porphyrazine 、 copper diacetate 以 氯苯 为溶剂， 以90-98的产率得到copper(II) 2,3,7,8,12,13,17,18-octakis(octylthio)-5,10,15,20-tetraazaporphyrine
  参考文献：
  名称：

  Doppelt, Pascal; Huille, Sylvain, New Journal of Chemistry, 1990, vol. 14, p. 607 - 610

  摘要：

  DOI：

文献信息

• Discotic mesomorphism of the 2,3,7,8,12,13,17,18-octakis- (octylthio) tetraazaporphyrin copper (II) complex
  作者：Giancarlo Morelli、Giampaolo Ricciardi、Antonio Roviello

  DOI：10.1016/0009-2614(91)80244-r

  日期：1991.10

  The free porphyrin 2,3,7,8,12,13,17,18-octakis(octylthio)tetraazaporphyrin (H2P8) and its copper(II) complex (CuP8) have been synthesized and studied by UV-VIS spectroscopy, calorimetric and X-ray analysis. The calorimetric analysis, as well the optical observations, indicate for CuP8 the existence of a liquid-crystalline mesophase between 67.6 and 151.7-degrees-C. The mesophase is characterized by X-ray diffraction at 81-degrees-C as discotic with an hexagonal arrangement of the columns. The stacking periodicity along the axes of the columns is almost-equal-to 4.1 angstrom, with a tilt angle of molecular planes estimated to be about 30-degrees.
• DOPPELT, PASCAL;HUILLE, SYLVAIN, NEW J. CHEM., 14,(1990) N-9, C. 607-609
  作者：DOPPELT, PASCAL、HUILLE, SYLVAIN

  DOI：——

  日期：——