A room temperature curing composition of this invention comprises an emulsion obtained by multi-stage emulsion polymerization of monomers, said emulsion comprising emulsion particles, a core of which comprises (A) 1 to 30 % by weight of silyl group-containing vinyl monomer, (B) 70 to 99 % by weight of vinyl monomer copolymerizable with component (A), the outermost shell of which comprises (A) 0.1 to 30 % by weight of silyl group-containing vinyl monomer and (B) 40 to 99.4 % by weight of vinyl monomer copolymerizable with component (A), and (D) 0.5 to 30 % by weight of hydrophilic vinyl monomer. The room temperature curing composition of this invention has a stable silyl group, and a much improved film-forming ability after long-term storage and it also shows excellent mechanical stability, water-resistance, durability and white enamel gloss.
本发明的室温固化组合物包括通过单体的多级乳液聚合得到的乳液,所述乳液包括乳液颗粒,其核心包括(A) 1-30%(按重量计)含
硅基的
乙烯基单体,(B) 70-99%(按重量计)可与组分(A)共聚的
乙烯基单体,其最外层包括(A) 0.1%至 30%(按重量计)的含
硅基
乙烯基单体和(B)40%至 99.4%(按重量计)的可与组分(A)共聚的
乙烯基单体,以及(D)0.5%至 30%(按重量计)的亲
水性
乙烯基单体。本发明的室温固化组合物具有稳定的
硅烷基,长期储存后成膜能力大为提高,还具有极佳的机械稳定性、耐
水性、耐久性和白色珐琅光泽。