Methyl 2,3,3,3-tetrafluoro-2-[1,1,2,3,3,3-hexafluoro-2-[(1,1,2-trifluoro-2-propen-1-yl)oxy]propoxy]-propanoate | 174082-83-8

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: Methyl 2,3,3,3-tetrafluoro-2-[1,1,2,3,3,3-hexafluoro-2-[(1,1,2-trifluoro-2-propen-1-yl)oxy]propoxy]-propanoate
• 英文别名: methyl 2,3,3,3-tetrafluoro-2-[1,1,2,3,3,3-hexafluoro-2-(1,1,2-trifluoroprop-2-enoxy)propoxy]propanoate
• CAS: 174082-83-8
• 化学式: C₁₀H₅F₁₃O₄
• 分子量: 436.127
• InChiKey: WASZGSRAJREZRS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.7
• 重原子数：
  27
• 可旋转键数：
  8
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.7
• 拓扑面积：
  44.8
• 氢给体数：
  0
• 氢受体数：
  17

文献信息

• FLUOROOLEFIN, FLUOROPOLYMER, AND THERMOPLASTIC RESIN COMPOSITION CONTAINING THE POLYMER
  申请人：DAIKIN INDUSTRIES, LIMITED

  公开号：EP0728776A1

  公开（公告）日：1996-08-28

  To provide a fluorine-containing olefin represented, for example, by CH2=CFCF2-Rf6-(CH2)k-X2 [wherein, X2 is -CH2OH, Rf6 is a fluorine-substituted fluorine-containing alkyl group having 1 to 40 carbon atoms or -ORf7- (Rf7 is a fluorine-substituted fluorine-containing alkyl group having 1 to 40 carbon atoms or a fluorine-substituted fluorine-containing ether group having 3 to 50 carbon atoms), k is 0 or an integer of 1 to 6]; a fluorine-containing polymer with functional group which is prepared by polymerizing the above-mentioned olefin, has good affinity with various heat-resisting thermoplastic resins and is capable of forming homogeneous dispersion with the thermoplastic resin; and a thermoplastic resin composition comprising the above-mentioned fluorine-containing polymer with functional group and an aromatic polyester or the like as the heat-resisting thermoplastic resin.

  提供一种含氟烯烃，例如由CH2=CFCF2-Rf6-( )k-X2[其中，X2是- OH、 Rf6 是具有 1 至 40 个碳原子的氟取代的含氟烷基或-ORf7-（Rf7 是具有 1 至 40 个碳原子的氟取代的含氟烷基或具有 3 至 50 个碳原子的氟取代的含氟醚基），k 是 0 或 1 至 6 的整数]；通过聚合上述烯烃制备的含氟官能团聚合物，该聚合物与各种耐热热塑性树脂具有良好的亲和性，并能与热塑性树脂形成均匀的分散体；以及由上述含氟官能团聚合物和作为耐热热塑性树脂的芳香族聚酯或类似物组成的热塑性树脂组合物。
• FLUORINATED MATERIAL FOR COATING COMPOSITION AND METHOD OF COATING USING THE SAME
  申请人：DAIKIN INDUSTRIES, LIMITED

  公开号：EP0866107A1

  公开（公告）日：1998-09-23

  To provide a fluorine-containing coating material which gives excellent adhesive strength directly to a substrate such as metal, glass, etc. with maintaining excellent characteristics of the fluorine-containing polymer such as thermal resistance, chemical resistance, non-sticking property and low friction property, and a method for coating the material. The fluorine-containing coating material is prepared by using a fluorine-containing ethylenic polymer having functional group which is obtained by copolymerizing (a-1) 0.05 to 30 % by mole of at least one of fluorine-containing ethylenic monomers having any one of functional groups selected from hydroxyl, carboxyl, carboxylate salt group, carboxylate ester group or epoxy and (b-1) 70 to 99.95 % by mole of at least one of fluorine-containing ethylenic monomers having no functional group mentioned above.

  提供一种含氟涂层材料，该材料可直接与金属、玻璃等基材产生优异的粘合强度，同时保持含氟聚合物的优异特性，如耐热性、耐化学性、不粘性和低摩擦性，并提供一种涂覆该材料的方法。含氟涂层材料的制备方法是使用一种具有官能团的含氟乙烯聚合物，该聚合物是由(a-1)0.05%至 30%（以摩尔计）的至少一种具有从羟基、羧基、羧酸盐基、羧酸酯基或环氧基中任选一种官能团的含氟乙烯单体和(b-1)70%至 99.95%（以摩尔计）的至少一种不具有上述官能团的含氟乙烯单体共聚而成。
• FLUOROADHESIVE AND ADHESIVE FILM AND LAMINATE PREPARED THEREFROM
  申请人：DAIKIN INDUSTRIES, LIMITED

  公开号：EP0866108A1

  公开（公告）日：1998-09-23

  To provide a fluorine-containing adhesive which maintains thermal resistance, chemical resistance, weather resistance and electric insulating property and has strong adhesive property directly to substrates particularly metal and glass, and an adhesive film and laminated article which are obtained by using the fluorine-containing adhesive. There is used a fluorine-containing ethylenic polymer having hydroxyl which is prepared by copolymerizing 0.05 to 30 % by mole of at least one of fluorine-containing ethylenic monomers having hydroxyl and 70 to 99.95 % by mole of at least one of fluorine-containing ethylenic monomers copolymerizable with the above-mentioned monomer.

  提供一种保持耐热性、耐化学性、耐候性和电绝缘性并对基材（尤其是金属和玻璃）直接具有强粘合性的含氟粘合剂，以及使用该含氟粘合剂获得的粘合薄膜和层压制品。本发明使用了一种含氟乙烯基羟基聚合物，该聚合物是由 0.05% 至 30% （摩尔）的至少一种含氟乙烯基羟基单体和 70% 至 99.95% （摩尔）的至少一种可与上述单体共聚的含氟乙烯基单体共聚而成。
• A laminated article and a fluorine-containing adhesive film formed therefrom
  申请人：Daikin Industries, Ltd.

  公开号：EP1110713A2

  公开（公告）日：2001-06-27

  A laminated article is provided which comprises: (A) a layer of an adhesive comprising a fluorine-containing ethylenic polymer having hydroxyl groups, the polymer being obtainable by copolymerizing: (a) 0.05 to 30 % by mole of at least one of fluorine-containing ethylenic monomer having hydroxyl; and (b) 70 to 99.95 % by mole of at least one fluorine-containing ethylenic monomer having no hydroxyl and which is copolymerizable with the monomer (a); and (B) a layer of an inorganic material or an organic material. The laminated article can be formed into a fluorine-containing adhesive film in which the layer (B) is formed from a fluorine-containing polymer having no functional group in its branched chain, a non-fluorine containing (organic) polymer, a metallic (inorganic) material, or a silicon-based (inorganic) material.

  提供的层压制品包括 (A) 一层粘合剂，该层粘合剂由具有羟基的含氟乙烯聚合物组成，该聚合物可通过共聚获得： (a) 0.05%至 30%(以摩尔计)的至少一种含氟乙烯基单体；和 (b) 70%至 99.95%（以摩尔计）的至少一种不含羟基且可与单体(a)共聚的含氟乙 烯单体；以及 (B) 无机材料或有机材料层。 层压制品可制成含氟胶膜，其中层(B)由支链中无官能团的含氟聚合物、不含氟（有机）聚合物、金属（无机）材料或硅基（无机）材料制成。
• OPTICAL MATERIAL CONTAINING FUNCTIONAL FLUOROPOLYMER
  申请人：Daikin Industries, Ltd.

  公开号：EP1375589A1

  公开（公告）日：2004-01-02

  There is provided an optical material obtained from an organic composition which is suitable for an optical material in optical communication and comprises a fluorine-containing polymer having functional group and a rare earth metal ion, in which the fluorine-containing polymer having functional group has at least one ketone structure in its side chain and a maximum absorption coefficient of not more than 1 cm-1 in each wavelength range of from 1,290 to 1,320 nm, from 1,530 to 1,570 nm and from 600 to 900 nm and the rare earth metal ion is at least one selected from the group consisting of erbium (Er) ion, thulium (Tm) ion, praseodymium (Pr) ion, holmium (Ho) ion, neodymium (Nd) ion and europium (Eu) ion.

  本发明提供了一种从有机组合物中获得的光学材料，该光学材料适用于光通信中的光学材料，由具有官能团的含氟聚合物和稀土金属离子组成，其中具有官能团的含氟聚合物的侧链中至少有一个酮结构，在1、290 至 1,320 纳米、1,530 至 1,570 纳米和 600 至 900 纳米范围内的最大吸收系数不超过 1 cm-1，而稀土金属离子至少选自由铒 (Er) 离子、铥 (Tm) 离子、镨 (Pr) 离子、钬 (Ho) 离子、钕 (Nd) 离子和铕 (Eu) 离子组成的组中的一种。