6,7-dimethyl-5,8-dihydro-[1,3,4]thiadiazolo[3,4-a]pyridazine-1,3-dione | 41316-19-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二嗪类
• 英文名称: 6,7-dimethyl-5,8-dihydro-[1,3,4]thiadiazolo[3,4-a]pyridazine-1,3-dione
• 英文别名: 4,5-dimethyl-3,6-dihydro-pyridazine-1,2-dicarboxylic acid thioanhydride；6,7-Dimethyl-5,8-dihydro[1,3,4]thiadiazolo[3,4-a]pyridazine-1,3-dione；6,7-dimethyl-5,8-dihydro-[1,3,4]thiadiazolo[3,4-a]pyridazine-1,3-dione
• CAS: 41316-19-2
• 化学式: C₈H₁₀N₂O₂S
• 分子量: 198.246
• InChiKey: CXNPMVZWZBUPJZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.5
• 重原子数：
  13
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  65.9
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  1-Thia-3,4-diazolidine-2,5-dione 以50%的产率得到
  参考文献：
  名称：

  Squiliacote Michael, De Felippis James, J. Org. Chem, 59 (1994) N 13, S 3564-3571

  摘要：

  DOI：

文献信息

• 1-Thia-3,4-diazolidine-2,5-dione functionality: a photochemical synthon for the azo group
  作者：Michael Squillacote、James De Felippis

  DOI：10.1021/jo00092a013

  日期：1994.7

  The 1-thia-3,4-diazolidine-2,5-dione functional group was shown to yield azo compounds upon photolysis. This photoreaction when combined with the known ability of this group to react in a Diels-Alder fashion or as a dinucelophile toward alkylating agents greatly increases the utility of this functionality. The dual reactivity of this group was demonstrated in the synthesis of a number of 3,4-dialkyl-1-thia-3,4-diazolidine-2,5-diones. The photolysis of these compounds produced either thermally stable cyclic azo compounds or the decomposition products of thermally unstable azo compounds.
• Syntheses and reactions of 3,4-dialkyl-1,3,4-thiadiazolidine-2,5-diones
  作者：Steven W. Moje、Peter Beak

  DOI：10.1021/jo00934a003

  日期：1974.10
• The Preparation of 1,3,4-Thiadiazoline-2,5-dione and Its Use as a Dienophilic Reagent
  作者：E. Corey、Barry Snider

  DOI：10.1021/jo00960a600

  日期：1973.10
• Squiliacote Michael, De Felippis James, J. Org. Chem, 59 (1994) N 13, S 3564-3571
  作者：Squiliacote Michael, De Felippis James

  DOI：——

  日期：——
• MOJE S. W.; BEAK P., J. ORG. CHEM. <JOCE-AH>, 1974, 39, NO 20, 2951-2956
  作者：MOJE S. W.、 BEAK P.

  DOI：——

  日期：——