manganese (III) deuteroporphyrin | 24842-92-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 四吡咯及其衍生物
• 英文名称: manganese (III) deuteroporphyrin
• CAS: 24842-92-0
• 化学式: C₃₀H₂₈MnN₄O₄
• 分子量: 563.515
• InChiKey: RBAGPJQAYIFCFS-RWRCOHKGSA-L

反应信息

• 作为产物：
  描述：

  deuteroporphyrin IX 在 manganese (II) acetate tetrahydrate 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 生成 manganese (III) deuteroporphyrin
  参考文献：
  名称：

  Biomimetic enhanced chemiluminescence of luminol–H2O2 system by manganese (III) deuteroporphyrin and its application in flow injection determination of phenol at trace level

  摘要：

  A novel, sensitive and high selective flow-injection chemiluminescence (FI-CL) method for the determination of phenol is reported, based upon its decreasing effect on the CL reaction of luminol with hydrogen peroxide catalyzed by manganese (III) deuteroporphyrin [MnDP, Scheme 1, 3] in alkaline solution. Under the selected optimized experimental conditions, the relative CL intensity was linear with phenol in the range of 4.0 x 10(-9) to 4.0 x 10(-7) g mL(-1). The detection limit (3 sigma) was 6.3 x 10(-10) g mL(-1) and the relative standard deviation for 1.0 x 10(-7) g mL(-1) phenol (n = 11) was 2.99%. The regression equation was I = 120.79 + 1.14 x 1010c (R = 0.9936). This method has been applied to the determination of phenol in water with satisfactory results. (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jphotochem.2011.10.021