N-(4-(diphenylphosphaneyl)phenyl)-3-formyl-2-hydroxybenzamide | 1263267-81-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N-(4-(diphenylphosphaneyl)phenyl)-3-formyl-2-hydroxybenzamide
• CAS: 1263267-81-7
• 化学式: C₂₆H₂₀NO₃P
• 分子量: 425.423
• InChiKey: RSBDOZDTRCQARW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.22
• 重原子数：
  31.0
• 可旋转键数：
  6.0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  66.4
• 氢给体数：
  2.0
• 氢受体数：
  3.0

反应信息

• 作为反应物：
  描述：

  苯 、 nickel diacetate 、 N-(4-(diphenylphosphaneyl)phenyl)-3-formyl-2-hydroxybenzamide 、 (1R,2R)-1,2-diaminocyclohexane 以 not given 为溶剂， 以92%的产率得到N,N'-bis-(N-phenyl(4-diphenylphosphine)-3-salicylidenato carboxamide)-(1R,2R)-cycloxexanediaminato-nickel(II) benzene octasolvate
  参考文献：
  名称：

  Weak absolute helicity direction in Ni–salen by trans-cyclohexane-(1R,2R)-diamine

  摘要：

  Helical Ni-salen foldamers were synthesized from enantiomerically pure cyclohexane-(1R,2R)-diamine, N, N'-bis-(N-phenyl (4-diphenylphosphine)-3-salicylidenato carboxamide)-(1R,2R)-cyclohexanediamina-to-nickel(II). X-ray structural characterization of the absolute helicities observed confirms our earlier assertions, based on solution spectroscopic evidence, that trans-cyclohexane-diamine, a common component of chiral salen catalysts, is a weak director of absolute helicity for Ni-salen. (C) 2010 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2010.07.044
• 作为产物：
  描述：

  对碘苯胺 在 potassium acetate 、 palladium diacetate 、 臭氧 、 三乙胺 作用下， 以 N,N-二甲基乙酰胺 为溶剂， 生成 N-(4-(diphenylphosphaneyl)phenyl)-3-formyl-2-hydroxybenzamide
  参考文献：
  名称：

  Weak absolute helicity direction in Ni–salen by trans-cyclohexane-(1R,2R)-diamine

  摘要：

  Helical Ni-salen foldamers were synthesized from enantiomerically pure cyclohexane-(1R,2R)-diamine, N, N'-bis-(N-phenyl (4-diphenylphosphine)-3-salicylidenato carboxamide)-(1R,2R)-cyclohexanediamina-to-nickel(II). X-ray structural characterization of the absolute helicities observed confirms our earlier assertions, based on solution spectroscopic evidence, that trans-cyclohexane-diamine, a common component of chiral salen catalysts, is a weak director of absolute helicity for Ni-salen. (C) 2010 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2010.07.044