1,4-diphenyl-1,4-butanediol bis(methanesulfonic acid ester) | 82631-96-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1,4-diphenyl-1,4-butanediol bis(methanesulfonic acid ester)
• 英文别名: (4-methylsulfonyloxy-1,4-diphenylbutyl) methanesulfonate
• CAS: 82631-96-7
• 化学式: C₁₈H₂₂O₆S₂
• 分子量: 398.501
• InChiKey: NHSSFDSFEORCOX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.2
• 重原子数：
  26.0
• 可旋转键数：
  9.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  86.74
• 氢给体数：
  0.0
• 氢受体数：
  6.0

反应信息

• 作为反应物：
  描述：

  1,4-diphenyl-1,4-butanediol bis(methanesulfonic acid ester) 在 lithium aluminium tetrahydride 、 15-冠醚-5 、 sodium hydride 作用下， 以 四氢呋喃 为溶剂， 生成 (meso)-2,5-diphenylcyclopentane-1,1-dimethanol
  参考文献：
  名称：

  Synthesis and characterization of new chiral palladium β-diimine complexes

  摘要：

  The synthesis and characterization of a range of chiral beta-diimine ligands and their complexes with palladium(II) has been investigated. The introduction of chirality can be easily achieved through a combination of both achiral and chiral building blocks. The absolute configuration of the stereochemical centers has been determined. In addition, representative X-ray structures of both ligands and complexes have been determined. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2006.10.064
• 作为产物：
  描述：

  1,2-联苯甲酰乙烷 在 lithium aluminium tetrahydride 、 三乙胺 作用下， 以 乙醚 、 二氯甲烷 为溶剂， 反应 18.0h， 生成 1,4-diphenyl-1,4-butanediol bis(methanesulfonic acid ester)
  参考文献：
  名称：

  Synthesis and characterization of new chiral palladium β-diimine complexes

  摘要：

  The synthesis and characterization of a range of chiral beta-diimine ligands and their complexes with palladium(II) has been investigated. The introduction of chirality can be easily achieved through a combination of both achiral and chiral building blocks. The absolute configuration of the stereochemical centers has been determined. In addition, representative X-ray structures of both ligands and complexes have been determined. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2006.10.064

文献信息

• Sato, Mitsuo; Gunji, Yasuhiko; Ikeno, Taketo, Synthesis, 2004, # 9, p. 1434 - 1438
  作者：Sato, Mitsuo、Gunji, Yasuhiko、Ikeno, Taketo、Yamada, Tohru

  DOI：——

  日期：——