| 395646-22-7

• 分子结构分类: 有机化合物 - 苯类化合物
• CAS: 395646-22-7
• 化学式: C₁₄H₁₁AlF₃NO₃S
• 分子量: 357.289
• InChiKey: XGRKPDWJVICLGG-UHFFFAOYSA-M

反应信息

• 作为反应物：
  描述：

  、 N,N-二甲基甲酰胺 生成
  参考文献：
  名称：

  Practical Approach to the Meerwein–Ponndorf–Verley Reduction of Carbonyl Substrates with New Aluminum Catalysts This work was partially supported by a Grant-in-Aid for Scientific Research from the Ministry of Education, Culture, Sports, Science and Technology, Japan.

  摘要：

  DOI：

  10.1002/1521-3773(20011001)40:19<3610::aid-anie3610>3.0.co;2-l
• 作为产物：
  描述：

  2-hydroxy-2'-(trifluoromethanesulfonylamino)biphenyl 、 三甲基铝 以 二氯甲烷 为溶剂， 生成
  参考文献：
  名称：

  Practical Approach to the Meerwein–Ponndorf–Verley Reduction of Carbonyl Substrates with New Aluminum Catalysts This work was partially supported by a Grant-in-Aid for Scientific Research from the Ministry of Education, Culture, Sports, Science and Technology, Japan.

  摘要：

  DOI：

  10.1002/1521-3773(20011001)40:19<3610::aid-anie3610>3.0.co;2-l
• 作为试剂：
  描述：

  2,3-diphenyl-2-triethylsiloxypropanal 在 C₁₂H₈(OAl(CH₃)N(SO₂CF₃)) 作用下， 以 甲苯 为溶剂， 生成 1,3-diphenyl-1-(triethylsiloxy)propan-2-one 、 1,3-Diphenyl-2-triethylsilyloxypropan-1-one
  参考文献：
  名称：

  Al Lewis acid-catalyzed regiodivergent 1,2-rearrangement of α-siloxy aldehydes: scope and mechanism

  摘要：

  Regiodivergent 1,2-rearrangement of alpha-siloxy aldehydes bearing alpha-aryl and alpha-alkyl substituents into alpha-siloxy ketones has been realized by using different Al Lewis acid catalyst/solvent systems. The scope of this unprecedented protocol has been investigated with various substrates, clearly demonstrating its utility for the selective synthesis of two structural isomers from one substrate. Controlled experiments proved that the regiodivergency resulted from the switch of the migrating group. (C) 2009 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2009.06.126