[Pd(N,N-diethylethylenediamine)Cl2] | 90911-07-2

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: [Pd(N,N-diethylethylenediamine)Cl2]
• 英文别名: [Pd(deen)Cl2]；dichloropalladium;N',N'-diethylethane-1,2-diamine
• CAS: 90911-07-2
• 化学式: C₆H₁₆Cl₂N₂Pd
• 分子量: 293.532
• InChiKey: JLMRENDEKVLZLE-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [Pd(N,N-diethylethylenediamine)Cl2] 、 乙二胺 以 N,N-二甲基甲酰胺 为溶剂， 生成
  参考文献：
  名称：

  N取代的乙二胺钯（II）配合物中配体置换的动力学

  摘要：

  取代的乙二胺，氯的速率- ，在基板[钯（R 2 N（CH 2）2 NR 2）氯2 ]和2,2'-联吡啶（BPY），在配合物[钯（BPY ）（R 2 N（CH 2）2 NR 2）]（R = H，甲基，乙基或苯基）分别在25°C下的二甲基甲酰胺和水中进行了研究。在两种方法中，反应速率取决于氮上取代基R的性质。虽然中性配合物的动力学数据可以简单地根据配体的电子和空间特性进行解释，但动力学常数的趋势似乎与各种配合物形成与水形成氢键的能力有关。

  DOI：

  10.1016/s0277-5387(97)88744-x
• 作为产物：
  描述：

  potassium tetrachloropalladate(II) 、 N,N-二乙基乙二胺 在 HCl or NaOH 作用下， 以 水 为溶剂， 生成 [Pd(N,N-diethylethylenediamine)Cl2]
  参考文献：
  名称：

  Speciation studies on the complex formation reactions of [Pd(N,N-diethyl-ethylendiamine)(H2O)2]2+ with some bio-relevant ligands and displacement reaction by mercaptoethylamine

  摘要：

  Pd(deen)Cl-2 and Pd(deen)(CBDCA) complexes, where deen = N,N-diethylethylenediamine and CBDCA = 1,1-cyclobutanedicarboxylate, were synthesized and characterized by elemental analysis and spectroscopic techniques. The stoichiometry and stability of the complexes formed between various biologically relevant ligands (amino acids, peptides, DNA constituents and dicarboxylic acids) and [Pd(deen)(H2O)(2)](2+) were investigated at 25 degrees C and 0.1 M ionic strength. The speciation diagrams of the complexes formed in solutions are evaluated. The mode of coordination of glycylglycine is investigated by spectrophotometric measurements. The equilibrium constants for the displacement of coordinated ligands as inosine, glycine or methionine by mercaptoethylamine are calculated. The results are expected to contribute to the chemistry of antitumour agents. (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.saa.2011.04.047

文献信息

• Optical Resolution and Circular Dichroism Spectra of Mixed-diamine Palladium(II) Complexes with Configurational Chirality
  作者：Kazuhiko Nakayama、Takashi Komorita、Yoichi Shimura

  DOI：10.1246/bcsj.54.1056

  日期：1981.4

  N1diethyl-1,2-propanediamine), were prepared and optically resolved (or separated in the case of the last named ligand) using diacetyl-d-tartaric anhydride as the resolving agent. Their electronic absorption and CD spectra were measured. A definite additivity has been confirmed between the configurational CD caused by the chiral configuration and the vicinal CD due to the asymmetric carbon atom in

  六个方形平面配合物，[PdL(meso-stien)](ClO4)2（meso-stien=meso-1,2-diphenyl-1,2-乙二胺；L=N,N-二乙基乙二胺，N,N-二甲基乙二胺, 2-甲基-1,2-丙二胺, N2,N2-二甲基-2-甲基-1,2-丙二胺, N, N-二甲基-1,3-丙二胺, 和 (2S)-N1,N1diethyl-1, 2-丙二胺），使用二乙酰-d-酒石酸酐作为拆分剂进行光学拆分（或在最后命名的配体的情况下分离）。测量了它们的电子吸收和 CD 光谱。由于 (2S)-N1,N1-二乙基-1,2-丙二胺络合物中的不对称碳原子，手性构型引起的构型 CD 和邻位 CD 之间已证实明确的可加性。
• Synthesis and Isomerism of Mixed (Amine)(carboxylato) Complexes with the [Pd(N)<i>_n</i>(O)_4−<i>n</i>]-type (<i>n</i>=1–4) and Their Circular Dichroism Spectra
  作者：Kazuhiko Nakayama、Takashi Komorita、Yoichi Shimura

  DOI：10.1246/bcsj.57.1240

  日期：1984.5

  A large number of mixed-ligand [Pd(N)n(O)4−n]-type complexes (n=1–4) which contain at least one optically active ligand were synthesized and isolated in a systematic manner. (S)-Propylenediamine, (2S)-N1,N1-diethyl-1,2-propanediamine, and (S)-amino carboxylates were employed as one ligand, which is optically active; ammonia, diamines, amino carboxylates, acetates, and dicarboxylates as the other ligand occupying the remaining coordination sites. Isomerism could be detected in the mixed complexes of an unsymmetrical diamine and an amino carboxylate and has been discussed on the basis of 13C NMR and CD spectra. Moreover, the influence of optically inactive ligands on the vicinal CD spectra has been examined, and also the additivity of vicinal CD contributions of two different optically active ligands has been demonstrated.

  以系统的方式合成和分离了大量含有至少一个光学活性配体的混合配体[Pd(N)n(O)4−n]型配合物(n=1-4)。采用(S)-丙二胺、(2S)-N1,N1-二乙基-1,2-丙二胺和(S)-氨基羧酸盐作为配体，具有光学活性；氨、二胺、氨基羧酸盐、乙酸盐和二羧酸盐作为占据剩余配位位点的其他配体。异构现象可以在不对称二胺和氨基羧酸盐的混合复合物中检测到，并且已经在 13C NMR 和 CD 光谱的基础上进行了讨论。此外，还研究了光学非活性配体对邻位圆二色光谱的影响，并且还证明了两种不同光学活性配体的邻位圆二色贡献的加和性。