[silver(3-(p-chlorophenyloxy)prop-1-inide)]n | 1319212-25-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: [silver(3-(p-chlorophenyloxy)prop-1-inide)]n
• 英文别名: (4-Cl-C6H4OCH2CCAg)n
• CAS: 1319212-25-3
• 化学式: C₉H₆AgClO
• 分子量: 273.467
• InChiKey: GCBQYXKRFUPPTB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.23
• 重原子数：
  12.0
• 可旋转键数：
  2.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.11
• 拓扑面积：
  9.23
• 氢给体数：
  0.0
• 氢受体数：
  1.0

反应信息

• 作为反应物：
  描述：

  乙腈 、 silver trifluoroacetate 、 [silver(3-(p-chlorophenyloxy)prop-1-inide)]n 、 silver tetrafluoroborate 以 水 、 乙腈 为溶剂， 以65%的产率得到Ag(3-(p-chlorophenyloxy)prop-1-inide)(Ag(trifluoroacetate))4(acetonitrile)2
  参考文献：
  名称：

  Silver(I)-organic networks constructed with flexible silver-ethynide supramolecular synthon o-, m-, p-Cl–C6H5OCH2CC⊃Agn (n = 4, 5)

  摘要：

  A series of five silver coordination polymers [(AgL1)center dot(AgCF3COO)(5)center dot(H2O)(3)] (1), [(AgL1)(2)center dot(AgCF3COO)(11)center dot(H2O)(6)] (2), [(AgL2)center dot(AgCF3COO)(3)center dot(H2O)] (3), [(AgL3)center dot(AgCF3COO)(4)center dot(CH3CN)(2)] (4), and [(AgL3)center dot(AgCF3COO)(7)center dot(CH3CN)(2)center dot(H2O)(2)] (5) have been constructed from three flexible anionic ligands HL1, HL2, and HL3 (HL1 = 1-chloro-2-(prop-2-ynyloxy)benzene, HL2 = 1-chloro-3-(prop-2-ynyloxy)benzene, HL3 = 1-chloro-4-(prop-2-ynyloxy)benzene). In these compounds, the invariable appearance of the mu(4)- and mu(5)-ligation modes of the ethynide moiety affirms the general utility of the flexible silver-ethynide supramolecular synthon o-, m-, p-Cl-C6H5OCH2C C superset of Ag-n (n = 4, 5) in coordination network assembly. Among them, Ag center dot center dot center dot Cl interaction plays a vital role in assembling the supramolecular structures in complexes 1-3. (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2011.05.002
• 作为产物：
  描述：

  1-氯-4-(2-丙炔-1-基氧基)苯 、 silver nitrate 在 triethylamine 作用下， 以 乙腈 为溶剂， 以85%的产率得到[silver(3-(p-chlorophenyloxy)prop-1-inide)]n
  参考文献：
  名称：

  Silver(I)-organic networks constructed with flexible silver-ethynide supramolecular synthon o-, m-, p-Cl–C6H5OCH2CC⊃Agn (n = 4, 5)

  摘要：

  A series of five silver coordination polymers [(AgL1)center dot(AgCF3COO)(5)center dot(H2O)(3)] (1), [(AgL1)(2)center dot(AgCF3COO)(11)center dot(H2O)(6)] (2), [(AgL2)center dot(AgCF3COO)(3)center dot(H2O)] (3), [(AgL3)center dot(AgCF3COO)(4)center dot(CH3CN)(2)] (4), and [(AgL3)center dot(AgCF3COO)(7)center dot(CH3CN)(2)center dot(H2O)(2)] (5) have been constructed from three flexible anionic ligands HL1, HL2, and HL3 (HL1 = 1-chloro-2-(prop-2-ynyloxy)benzene, HL2 = 1-chloro-3-(prop-2-ynyloxy)benzene, HL3 = 1-chloro-4-(prop-2-ynyloxy)benzene). In these compounds, the invariable appearance of the mu(4)- and mu(5)-ligation modes of the ethynide moiety affirms the general utility of the flexible silver-ethynide supramolecular synthon o-, m-, p-Cl-C6H5OCH2C C superset of Ag-n (n = 4, 5) in coordination network assembly. Among them, Ag center dot center dot center dot Cl interaction plays a vital role in assembling the supramolecular structures in complexes 1-3. (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2011.05.002