trans-DPh-TTF | 72580-01-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: trans-DPh-TTF
• 英文别名: Diphenyltetrathiafulvalen；4,4'-Diphenyl-[2,2']bi[[1,3]dithiolylidene]；(2E)-4-phenyl-2-(4-phenyl-1,3-dithiol-2-ylidene)-1,3-dithiole
• CAS: 72580-01-9
• 化学式: C₁₈H₁₂S₄
• 分子量: 356.557
• InChiKey: UXYULNILNJCKTO-ISLYRVAYSA-N

物化性质

• 沸点：
  462.9±45.0 °C(Predicted)
• 密度：
  1.430±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5.8
• 重原子数：
  22
• 可旋转键数：
  2
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  101
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  trans-DPh-TTF 在 copper(l) iodide 、 四(三苯基膦)钯 氢氧化钾 、 全氟己基碘烷 、 三乙胺 、 lithium diisopropyl amide 作用下， 以 四氢呋喃 、 甲醇 、 乙醚 为溶剂， 反应 16.0h， 生成 (E)-4,4'-Diethynyl-5,5'-diphenyl-[2,2']bi[[1,3]dithiolylidene]
  参考文献：
  名称：

  Preparation of New Tetrathiafulvalene (TTF) Derivatives with Two Functional Groups at Symmetrical Positions: 2,6-Diiodo-3,7-diphenyl-TTF, 2,6-Bis[2-(trimethylsilyl)-ethynyl]-3,7-diphenyl-TTF, and 2,6-Diethynyl-3,7-diphenyl-TTF

  摘要：

  DOI：

  10.1055/s-1998-2033
• 作为产物：
  描述：

  2-methyl-4-phenyl-1,3-dithiole 以13%的产率得到
  参考文献：
  名称：

  SAEVA, F. D.;MORGAN, B. P.;FICHTNER, M. W.;HALEY, N. F., J. ORG. CHEM., 1984, 49, N 2, 390-391

  摘要：

  DOI：

文献信息

• Synthesis and electrochemical studies of tetrathiafulvalene derivatives (TTFs) as redox active ligands
  作者：Abd El-Wareth A. O. Sarhan、Makoto Murakami、Taeko Izumi

  DOI：10.1002/jhet.5570390413

  日期：2002.7

  simple route for synthesis of new tetrathiafulvalene dimethyl ester (TTF-DME) is reported. The tetrathifulvalene dimethylester (TTF-DME) has been prepared by introducing an ester coordination function as a bifunctional new donor. The redox behavior of the TTF-DME was investigated in comparison to the well-known dibenzotetrathiafulvene (DB-TTF) by cyclic voltammetry. A two-electron redox behavior was observed

  报道了合成新的四硫富瓦烯二甲基酯（TTF-DME）的简单途径。四硫富瓦烯二甲酯（TTF-DME）是通过引入酯配位官能团作为双功能新供体而制备的。通过循环伏安法，与已知的二苯并四硫富烯（DB-TTF）相比，研究了TTF-DME的氧化还原行为。观察到两波的两电子氧化还原行为。
• ACCUMULATOR MATERIAL AND ACCUMULATOR DEVICE
  申请人：Hojo Nobuhiko

  公开号：US20110091767A1

  公开（公告）日：2011-04-21

  An electricity storage device including a positive electrode 31 , a negative electrode 32 , and an electrolytic solution 29 located between the positive electrode and the negative electrode. At least one of the positive electrode 31 and the negative electrode 32 contains an electricity storage material containing a polymerization product having a tetrachalcogenofulvalene structure in a repeat unit of a main chain.

  一种电力储存装置，包括正极31、负极32和位于正极和负极之间的电解质29。正极31和负极32中的至少一个包含一种电力储存材料，该电力储存材料包含一个具有四硫属富瓦烯结构的聚合物化合物，在主链的重复单元中。
• POLYMER, SEMICONDUCTOR FILM, ELECTRODE, ELECTRODE ACTIVE MATERIAL, ELECTROCHEMICAL ELEMENT AND ELECTRICITY STORAGE DEVICE
  申请人：Panasonic Corporation

  公开号：EP2308912A1

  公开（公告）日：2011-04-13

  A polymer having a structure represented by the following general formula (1), wherein in general formula (1), Ph is a phenyl group; X is an oxygen atom, a sulfur atom, a selenium atom or a tellurium atom; and R1 and R1 each independently contains at least one selected from the group consisting of a chained saturated hydrocarbon group, a chained unsaturated hydrocarbon group, a cyclic saturated hydrocarbon group, a cyclic unsaturated hydrocarbon group, a phenyl group, a hydrogen atom, a hydroxyl group, a cyano group, an amino group, a nitro group and a nitroso group. The chained saturated hydrocarbon group, the chained unsaturated hydrocarbon group, the cyclic saturated hydrocarbon group and the cyclic unsaturated hydrocarbon group each contain at least one selected from the group consisting of a carbon atom, an oxygen atom, a nitrogen atom, a sulfur atom and a silicon atom.

  一种具有以下通式（1）所代表结构的聚合物，其中在通式（1）中，Ph 是苯基；X 是氧原子、硫原子、硒原子或碲原子；R1和R1各自独立地包含至少一个选自以下组成的组的基团：链状饱和烃基、链状不饱和烃基、环状饱和烃基、环状不饱和烃基、苯基、氢原子、羟基、氰基、氨基、硝基和亚硝基。链状饱和烃基、链状不饱和烃基、环状饱和烃基和环状不饱和烃基各自含有至少一个选自碳原子、氧原子、氮原子、硫原子和硅原子的基团。
• ACTUATOR ELEMENT USING CARBON ELECTRODE
  申请人：National Institute Of Advanced Industrial Science

  公开号：EP2833542A1

  公开（公告）日：2015-02-04

  An object of this invention is to create an actuator in which the amount of deformation is maintained and no displacement in the reverse direction occurs, even when a constant voltage is continuously applied for a long period of time. As a means for achieving the above object, the invention provides a conductive thin film comprising a polymer gel containing at least one organic molecule selected from the group consisting of electron-donating organic molecules and electron-withdrawing organic molecules, a nano-carbon material, an ionic liquid, and a polymer.

  本发明的一个目的是制造一种致动器，在这种致动器中，即使长时间连续施加恒定电压，也能保持一定的变形量，并且不会发生反向位移。 作为实现上述目的的一种方法，本发明提供了一种导电薄膜，该薄膜由聚合物凝胶组成，聚合物凝胶含有至少一种有机分子，该有机分子选自由电子供能有机分子和电子吸能有机分子、纳米碳材料、离子液体和聚合物组成的组。
• Actuator element using carbon electrode
  申请人：NATIONAL INSTITUTE OF ADVANCED INDUSTRIAL SCIENCE AND TECHNOLOGY

  公开号：US10367429B2

  公开（公告）日：2019-07-30

  An object of this invention is to create an actuator in which the amount of deformation is maintained and no displacement in the reverse direction occurs, even when a constant voltage is continuously applied for a long period of time. As a means for achieving the above object, the invention provides a conductive thin film comprising a polymer gel containing at least one organic molecule selected from the group consisting of electron-donating organic molecules and electron-withdrawing organic molecules, a nano-carbon material, an ionic liquid, and a polymer.

  本发明的一个目的是制造一种致动器，在这种致动器中，即使长时间连续施加恒定电压，也能保持一定的变形量，并且不会发生反向位移。 作为实现上述目的的一种方法，本发明提供了一种导电薄膜，该薄膜由聚合物凝胶组成，聚合物凝胶含有至少一种有机分子，该有机分子选自由电子供能有机分子和电子吸能有机分子、纳米碳材料、离子液体和聚合物组成的组。