(E,E)-2,5-Dichlor-N,N'-dicyan-1,4-benzochinondiimin | 97954-67-1

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: (E,E)-2,5-Dichlor-N,N'-dicyan-1,4-benzochinondiimin
• 英文别名: 2,5-dichloro-N,N'-dicyano-1,4-benzoquinonediimine
• CAS: 97954-67-1
• 化学式: C₈H₂Cl₂N₄
• 分子量: 225.037
• InChiKey: HZMXWMYLKXURLH-FNCQTZNRSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.09
• 重原子数：
  14.0
• 可旋转键数：
  0.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  72.3
• 氢给体数：
  0.0
• 氢受体数：
  4.0

反应信息

• 作为反应物：
  描述：

  四硫富瓦烯 、 (E,E)-2,5-Dichlor-N,N'-dicyan-1,4-benzochinondiimin 以 乙腈 为溶剂， 以98%的产率得到2-(1,3-Dithiol-2-yliden)-1,3-dithiol, CT-Komplex mit (E,E)-2,5-Dichlor-N,N'-dicyan-1,4-benzochinondiimin (1:1)
  参考文献：
  名称：

  Aumueller, Alexander; Erk, Peter; Huenig, Siegfried, Liebigs Annalen der Chemie, 1987, p. 997 - 1006

  摘要：

  DOI：
• 作为产物：
  描述：

  2,5-二-氯-1,4-苯二胺 在 lead(IV) acetate 、 ammonium hydroxide 、 lead acetate 、 三乙胺 作用下， 以 四氢呋喃 、 氢氧化钾 、 氯仿 、 溶剂黄146 为溶剂， 反应 48.1h， 生成 (E,E)-2,5-Dichlor-N,N'-dicyan-1,4-benzochinondiimin
  参考文献：
  名称：

  Andreetti, Giovanni D.; Bradamante, Silvia; Bizzarri, Paolo Costa, Molecular Crystals and Liquid Crystals (1969-1991), 1985, vol. 120, p. 309 - 314

  摘要：

  DOI：

文献信息

• LIGHT EMITTING ELEMENT
  申请人：Toray Industries, Inc.

  公开号：EP2595208A1

  公开（公告）日：2013-05-22

  Provided is an organic thin film light emitting element which has achieved all of improved luminous efficiency, improved driving voltage and improved durability life. Specifically provided is a light emitting element which comprises a hole transport layer and an electron transport layer between a positive electrode and a negative electrode and emits light by means of electrical energy. The light emitting element is characterized in that: the hole transport layer of the light emitting element contains a compound represented by general formula (1); the electron transport layer contains a donor compound; and the donor compound is an alkali metal, an inorganic salt containing an alkali metal, a complex of an alkali metal and an organic substance, an alkaline earth metal, an inorganic salt containing an alkaline earth metal, or a complex of an alkaline earth metal and an organic substance. (In the formula, R1-R20 each represents one group selected from the group consisting of hydrogen, deuterium, an alkyl group, a cycloalkyl group, an amino group, an aryl group, a heterocyclic group, a heteroaryl group, an alkenyl group, a cycloalkenyl group, an alkynyl group, analkoxy group, an alkylthio group, an arylether group, an arylthioethergroup, a halogen, a cyano group, a -P(=O)R24R25 group and a silyl group;R24 and R25 each represents an aryl group or a heteroaryl group; and these substituents may be further substituted, or adjacent two substituents may combine together to form a ring. Meanwhile, R21-R23 may be the same or different and each represents one group selected from the group consisting of an alkyl group, a cycloalkyl group, an aryl group and a heteroaryl group; and these substituents maybe further substituted.)

  本发明提供了一种有机薄膜发光元件，它实现了发光效率的提高、驱动电压的提高和耐用寿命的提高。具体地说，本发明提供了一种发光元件，它包括位于正极和负极之间的空穴传输层和电子传输层，并通过电能发光。该发光元件的特征在于：发光元件的空穴传输层含有通式（1）表示的化合物；电子传输层含有供体化合物；供体化合物是碱金属、含碱金属的无机盐、碱金属和有机物的复合物、碱土金属、含碱土金属的无机盐或碱土金属和有机物的复合物。(式中，R1-R20 各代表一个选自氢、氘、烷基、环烷基、氨基、芳基、杂环基、杂芳基、烯基、环烯基、炔基、烷氧基、烷硫基、芳醚基、芳硫醚基、卤素、氰基、-P(=O)R24R25 基和硅烷基的基团；R24 和 R25 分别代表芳基或杂芳基；这些取代基可以进一步被取代，或者相邻的两个取代基可以结合在一起形成一个环。同时，R21-R23 可以相同或不同，各自代表一个选自烷基、环烷基、芳基和杂芳基的基团；这些取代基可能被进一步取代）。
• FLUORANTHENE DERIVATIVE, LUMINESCENT ELEMENT MATERIAL CONTAINING SAME, AND LUMINESCENT ELEMENT
  申请人：Toray Industries, Inc.

  公开号：EP2907803A1

  公开（公告）日：2015-08-19

  The purpose of the present invention is to provide an organic thin-film luminescent element which exhibits improved luminous efficiency, drive voltage and durability life. This fluoranthene derivative is characterized by having a specificstructure that contains a fluoranthene skeleton.

  本发明的目的是提供一种有机薄膜发光元件，其发光效率、驱动电压和耐用寿命均有所提高。这种荧蒽衍生物的特点是具有包含荧蒽骨架的特定结构。
• AUMUELLER, A.;HUENIG, S., LIEBIGS ANN. CHEM., 1986, N 1, 142-164
  作者：AUMUELLER, A.、HUENIG, S.

  DOI：——

  日期：——
• FLUORANTHENE DERIVATIVE, LIGHT-EMITTING DEVICE MATERIAL CONTAINING SAME, AND LIGHT-EMITTING DEVICE
  申请人：TORAY INDUSTRIES, INC.

  公开号：US20150280139A1

  公开（公告）日：2015-10-01

  The purpose of the present invention is to provide an organic thin-film luminescent element which exhibits improved luminous efficiency, drive voltage and durability life. This fluoranthene derivative is characterized by having a specific structure that contains a fluoranthene skeleton.
• PHENANTHROLINE DERIVATIVE, ELECTRONIC DEVICE CONTAINING SAME, LIGHT EMITTING ELEMENT, AND PHOTOELECTRIC CONVERSION ELEMENT
  申请人：TORAY INDUSTRIES, INC

  公开号：US20180019407A1

  公开（公告）日：2018-01-18

  Provided is a phenanthroline derivative having a specific structure. The phenanthroline derivative includes in a skeleton a substituted or unsubstituted heteroaryl group having electron-accepting nitrogen, and a substituted or unsubstituted aryl group having less than 20 ring-forming carbon atoms. The phenanthroline derivative is preferably used in electronic devices such as light emitting elements, photoelectric conversion elements, lithium ion batteries, fuel cells and transistors.